In International Conference on Advances in
Mechanical Engineering (ICAME)
Concorde Hotel, Shah Alam, Malaysia, 24-25 June 2009
Electrical Conductive Carbon
Nanotubes/Graphite/Polypropylene Nanocomposites
Abu
Bakar Sulong, Hasanal Izwan Abdul Wahab, Zulkifli Selamat, and Jaafar
Sahari
Correspondence author: abubakar@eng.ukm.my
Fuel Cell
Institute, Department of Mechanical and Materials Engineering,
Faculty of
Engineering & Built Environment, Universiti Kebangsaan Malaysia,
43600 Bangi,
Selangor, Malaysia
Abstract
Better
chemical corrosion, lowering manufacturing cost and significant
reduction of total mass of bipolar plate in Proton Exchange Membrane
Fuel Cell (PEMFC) lead most of the PEMFC’s researchers over the world
shown their interest to replace metal based bipolar plate to conductive
polymer composites (CPCs) bipolar plate. Conductive fillers such as
carbon black and graphite had been incorporated in Polypropylene (PP)
matrix for fabrication of electrical conductive polymer composite plate.
Most researchers reported only at high loading of fillers (more than 90
wt%), PP CPCs gave electrical conductivity above 100 S/cm, which is
target from Department of Energy (USA). Higher loading of fillers cause
change in rheological properties lead to difficulties in polymer
processing. It also leads to decreasing of mechanical properties of CPCs.
Therefore, in this study carbon nanotubes which have 1000 time
electrical conductivity than copper wire are introduced into PP matrix
with graphite to compensate above problems. Electrical conductivity is
measured at in-plane of CPCs, and morphology study by optical
microscope. Addition of CNTs resulted in significantly decreases the
resistivity of CPCs. Therefore, graphite loading fraction can be
reducing by addition of CNTs, in order to maintain process ability of
CPCs, especially in injection molding.
Keywords:
nanomaterial fillers, electrical conductive polymer composites, carbon
nanotubes
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