The Malaysian Journal of Analytical Sciences Vol 11 No 1 (2007): 331 – 335

 

 

MORPHOLOGICAL STUDIES OF DHSA/DHSA-OCTYL ESTER/RBD PALM KERNEL OLEIN/MEDIUM CHAIN TRIGLYCERIDES SYSTEM

 

Anuar Kassim1, Rathidevi Nadarajan1 , Zahariah Ismail2 , Mohd Zaizi Desa1, Atan Mohd Sharif1 ,

Dzulkefly Kuang1  and Md Jelas Haron1

 

1Department of Chemistry, Faculty of Science, University Putra Malaysia,

43400 UPM Serdang Selangor.

2Golden Hope Research Centre, 42700, Banting Selangor.

 

Abstract

Dihydroxystearic  acid (DHSA) and octyl dihydroxystearate (DHSA-octyl ester) have been previously prepared from palm oleic acid and preliminary results showed that these compounds are suitable in personal care and cosmetics products. The objective of this research is to study the phase behavior in ternary system of DHSA/DHSA-octyl ester/RBD Palm Kernel Olein (RBDPKOo) & MCT at 85oC. From the ternary phase diagram, results showed that all ratios of were completely in two-phase region with various concentrations of RBDPKOo and MCT. The phase changes were observed through polarizing light while the formation  of texture was confirmed  using polarizing  microscope  combination  with  heating. Needles and spherulite textures were found in this system.

 

Keywords: Dihydroxystearic Acid, octyl dihydroxystearate, RBD palm kernel olein, medium chain triglycerides,

ternary phase diagram.

 

References

1.         Awang,R., Ahmad,S.,,Kang, YB. And Masrie,R.,(2001). Characterization of Dihydroxystearic Acid from Palm Oleic Acid,J.American of Oil Chem.Soc. 78(12): 1249-1252.

2.         Awang,  R.,  Ahmad,S.,  and  Kang,  Y.B.  (1998).Preparation  of Dihydroxyfatty  Acid from Oleic  Acid,Malaysian Patent, PI 9804456

3.         Awang,R.,Basri,M.,Ahmad,S.,  and Salleh.,A.B.,(2000). Enzymatic  Esterification Of Dihydroxystearic Acid, Inform J9248 in JAOCS (11),609-612.

4.         Awang,   R.,   Ahmad,S.,   and   Ghazali.   R.   (2001).   Properties   of   Sodium   Soap   Derived   from   Palm-based Dihydroxystearic Acid, J.Oil Palm Research 13(2): 33-38.

5.         Hayes,   D.G;  and  Kleiman,   R.M.   Lipase-catalyzed  synthesis   of  lesquerolic   acid  Wax  and   oil  esters  and theirproperties, J.Am. Oil Chem.Soc., 1996,73,1385-1392.

6.         Rigano, L.Report on study of the possible cosmetic application of a new hydroxylated palm oil derivatives , Milan Italy, 2001.




Previous                    Content                    Next