The
Malaysian Journal of Analytical Sciences Vol 11 No 1 (2007): 331 – 335
MORPHOLOGICAL STUDIES OF DHSA/DHSA-OCTYL ESTER/RBD
PALM KERNEL OLEIN/MEDIUM CHAIN TRIGLYCERIDES SYSTEM
Anuar Kassim1, Rathidevi Nadarajan1
, Zahariah Ismail2 , Mohd Zaizi Desa1, Atan Mohd Sharif1
,
Dzulkefly Kuang1 and Md Jelas Haron1
1Department of Chemistry, Faculty of Science,
University Putra Malaysia,
43400 UPM Serdang
Selangor.
2Golden Hope Research Centre, 42700, Banting
Selangor.
Abstract
Dihydroxystearic acid (DHSA) and octyl dihydroxystearate (DHSA-octyl
ester) have been previously prepared from palm oleic acid and preliminary
results showed that these compounds are suitable in personal care and cosmetics
products. The objective of this research is to study the phase behavior in
ternary system of DHSA/DHSA-octyl ester/RBD Palm Kernel Olein (RBDPKOo) &
MCT at 85oC. From the ternary phase diagram, results showed that all
ratios of were completely in two-phase region with various concentrations of
RBDPKOo and MCT. The phase changes were observed through polarizing light while
the formation of texture was
confirmed using polarizing microscope
combination with heating. Needles and spherulite textures were
found in this system.
Keywords:
Dihydroxystearic Acid, octyl dihydroxystearate, RBD palm kernel olein, medium
chain triglycerides,
ternary phase diagram.
References
1.
Awang,R., Ahmad,S.,,Kang, YB. And
Masrie,R.,(2001). Characterization of Dihydroxystearic Acid from Palm Oleic Acid,J.American
of Oil Chem.Soc. 78(12): 1249-1252.
2.
Awang, R.,
Ahmad,S., and Kang,
Y.B. (1998).Preparation of Dihydroxyfatty Acid from Oleic Acid,Malaysian Patent, PI 9804456
3. Awang,R.,Basri,M.,Ahmad,S., and Salleh.,A.B.,(2000). Enzymatic Esterification Of Dihydroxystearic Acid,
Inform J9248 in JAOCS (11),609-612.
4.
Awang, R.,
Ahmad,S., and Ghazali.
R. (2001). Properties
of Sodium Soap
Derived from Palm-based Dihydroxystearic Acid, J.Oil Palm
Research 13(2): 33-38.
5.
Hayes, D.G;
and Kleiman, R.M.
Lipase-catalyzed synthesis of
lesquerolic acid Wax
and oil esters
and theirproperties, J.Am. Oil Chem.Soc., 1996,73,1385-1392.
6.
Rigano, L.Report on study of the
possible cosmetic application of a new hydroxylated palm oil derivatives ,
Milan Italy, 2001.