Malaysian Journal of Analytical Sciences Vol 19 No 2
(2015): 318 324
SURFACE
SEDIMENT ANALYSIS ON PETROLEUM HYDROCARBON AND TOTAL ORGANIC CARBON FROM COASTAL AREA OF PAPAR TO TUARAN, SABAH
(Analisis Sedimen Permukaan Terhadap Petroleum
Hidrokarbon dan Jumlah Karbon Organik daripada Pesisiran Pantai Papar ke Tuaran,
Sabah)
Siti Aishah Mohd Ali1*, Carolyn Payus1, Masni Mohd
Ali2
1Water Research Unit, Faculty of Science and Natural
Resources,
Universiti Malaysia Sabah, Jalan UMS, 88400 Kota
Kinabalu, Sabah, Malaysia
2School of
Environmental and Natural Resource Sciences, Faculty of Science and Technology,
Universiti Kebangsaan Malaysia, 43600 UKM Bangi,
Selangor, Malaysia
*Corresponding author: ctaishah@ums.edu.my
Received: 12
September 2014; Accepted: 5 January 2015
Abstract
Total
petroleum hydrocarbons (TPH) and total organic carbon (TOC) were investigated
in surface sediments along coastal area of Papar to Tuaran, Sabah. Surface sediment samples were
collected in 24 different stations in each area by using Ponar grab sampler.
Samples were extracted for TPH using standard method sediment/sludge APHA 5520E
and analyzed using UV/VIS spectrophotometer while for TOC method analysis using
United Nations Environment Programme (UNEP)/MAP Athens
(2006). The range of TPH concentrations in surface sediments were recorded at 0.24
20.65 mg/kg dw Miri crude oil equivalents, meanwhile the TOC percentage ranged
from 0.03 4.02%. In the mean time, the statistical analysis by Pearson
correlation showed a positive
correlation with coefficient, r = 0.790 which showing the TPH concentrations
significantly have influence on the TOC accumulations in the surface sediment.
Keywords: total petroleum hydrocarbon, surface sediment, total
organic carbon
Abstrak
Jumlah petroleum hidrokarbon (TPH) dan jumlah karbon organik (TOC) telah dikaji dalam sedimen permukaan di sepanjang kawasan persisiran pantai Papar ke Tuaran, Sabah. Sampel sedimen permukaan dikumpul di
24 stesen yang berbeza di setiap kawasan dengan menggunakan Ponar grab sampler. Sampel telah diekstrak bagi TPH menggunakan kaedah piawai sedimen /enapcemar
APHA 5520E dan
dianalisis menggunakan UV/VIS
spektrofotometer manakala bagi kaedah analisis TOC pula
menggunakan United
Nations Environment Programme (UNEP)/MAP Athens
(2006). Julat kepekatan TPH dalam sedimen permukaan direkodkan pada 0.24 20.65 mg / kg bk setara
dengan minyak mentah Miri, sementara peratusan TOC adalah di antara 0.03
4.02%. Sementara itu, analisis statistik
dengan korelasi Pearson
menunjukkan korelasi positif dengan pekali, r = 0.790 yang menunjukkan kepekatan TPH
ketara mempunyai pengaruh ke atas
pengumpulan TOC dalam
sedimen permukaan.
Kata kunci: jumlah petroleum hidrokarbon, sedimen
permukaan, jumlah karbon organik
References
1.
Diyauddeen, B.H., Ashri Wan Daud, W.M. & Abdul
Aziz, A.R. (2011). Treatment technologies for petroleum refinery effluents: A
review. Process Safety and Environmental Protection. 89: 95-105.
2.
Al Darwish, H.A., Abd El-Gawad, E.A., Mohammed,
F.H. & Lotfy, M.M. (2005). Assessment of organic pollutants in the offshore
sediments of Dubai, United Arab Emirates. Environmental
Geology. 48: 531542.
3.
Venkatachalapathy,
R., Veerasingam, S., Basavaiah, N. & Ramkumar, T. (2010). Comparison
between petroleum hydrocarbon concentrations and magnetic properties in Chennai
coastal sediments, Bay of Bengal, India. Marine
and Petroleum Geology, 27: 1927-1935.
4.
Zanardi, E., Bicego, M.C., Miranda, L.B. & Weber, R.R. (1999).
Distribution and origin of hydrocarbon in water and sediment in Sao Sebastiao,
Brazil. Marine Pollution Bulletin,
38: 261 267.
5.
GESAMP.
(1993). Impact of oil and related chemicals and wastes on the marine
environment. In: Report and Studies, GESAMP. 50: 180.
6.
Laws,
E.A. (2000). Aquatic pollution: An
introductory text. John Wiley and Sons, Inc., New York, pp. 432-479.
7.
Wang,
Z. & Fingas, M.F. (2003). Development of oil hydrocarbon fingerprinting and
identification techniques. Marine
Pollution Bulletin, 47: 423-452.
8.
Choi,
H.G., Moon, H.B., Choi, M. & Yu, J. (2011). Monitoring of organic
contaminants in sediments from the Korean Coast: Spatial distribution and
temporal trends (2001-2007). Marine
Pollution Bulletin, 62(6): 1352-1361.
9.
Millie,
G., Asia, L., Guiliano, M., Malleret, L. & Dumenq, P. (2007). Hydrocarbon
in coastal sediments from the Mediterranean Sea (Gulf of Fos area, France). Marine Pollution Bulletin, 54: 566-575.
10. Maioli, O.L.G.,
Rodrigues, K.C., Knoppers, B.A. & Azevedo, D.A. (2010). Pollution source
evaluation using petroleum and aliphatic hydrocarbons in surface sediments from
two Brazilian estuarine systems. Organic
Geochemistry, 41: 966-970.
11. Baudouin, C.,
Charveron, M., Tarroux, R. & Gall, Y. (2007). Environmental pollutants and
skin cancer. Cell Biological Toxicology,
18: 341-348.
12. Kucuksezgin, F., Kontas, A.,
Altay, O., Uluturhan, E. & Darilmaz, E. (2006). Assessment of marine
pollution in Izmir Bay: Nutrient, heavy metal and total hydrocarbon
concentrations. Environment International,
32: 41-51.
13. Medeiros, P. M.,
Bcego, M. C., Castelao, R. M., Rosso, C. D., Fillmann, G. & Zamboni, A. J.
(2005). Natural and anthropogenic hydrocarbon inputs to sediments of Patos
Lagoon Estuary, Brazil. Environment
International, 31: 7787.
14. Lick, W. (2009). Sediment and contaminant transport in
surface water. CRC Press. America.
15. Hostettler, F.
D., Pereira, W. E., Kvenvolden, K. A., Green, V. A., Luoma, S. N., Fuller, C.
C. & Anima, R. (1999). A record of hydrocarbon input to San Francisco Bay
as traced by biomarker profiles in surface sediment and sediment core. Marine Chemistry, 64: 115127.
16. Lyla, S,
Manokaran, S. & Khan, A. (2012). Petroleum
hydrocarbon distribution in continental shelf region of southeast coast of
India. International Journal of Sediment
Research, 27: 73-83.
17. Niemirycz, E., Gozdek J. & Koszka-Maroń, D. (2006). Variability
of organic carbon in water and sediments of the Odra River and its tributaries.
Polish Journal of
Environmental Studies, 15. (4): 557-563.
18. Zerbe, J. (1993). Hydrocarbons and
its derivatives in water. Environmental and Natural Resources Protection.
19. Al-Abdali, F., Massoud, M.S. &
A1-Ghadban, A.N. (1996). Bottom sediments of the Arabian Gulf; IIL Trace metal
contents as indicators of pollution and implications for the effect and fate of
Kuwait oil slick. Environmental Pollution,
93(3): 285-301.
20. Massoud, M.S., AI-Abdali, F. &
AI-Ghadban, A.N. (1996). Bottom sediments of the Arabian Gulf; II. TPH and TOC
contents as indicators of oil pollution and implications for the effect and
fate of Kuwait oil slick. Environmental Pollution,
93(3): 271-284.
21. American Public Health Association (APHA). (2005).
Standard Methods for the Examination of Water and Wastewater. 21st Edition.
American Public Health Association.
22. United Nations Environment Programme (UNEP). (2006).
Methods for sediment sampling and analysis. United Nations Environment Program.
23. Marchand, M., Bodennec, G., Caprais, J.C. & Pignet, P. 1982. The AMOCO CADIZ
oil spill, distribution and evolution of oil pollution in marine sediments. In:
Ecological Study of the AMOCO CADIZ Oil Spill. Report of the NOAA-CNEXO Joint
Scientific Commission. pp. 143-157.
24. Suratman, S.,
Mohd Tahir. N. & Latif, M.T. (2012). A preliminary study of Total
Petrogenic Hydrocarbon distribution in Setiu Wetland, Southern South China Sea
(Malaysia). Bulletin of Environmental
Contamination Toxicolology, 88:755758.
25. Sutarji Kasmin.
(2010). Enforcing ship-based marine
pollution for cleaner sea in the Strait of Malacca. Environment Asia, 3: 61-65.
26. Hafidz B.
Yusoff, Zaini B. Assim & Samsur B. Mohamad. (2012). Aliphatic hydrocarbons
in surface sediments from South China Sea off Kuching Division, Sarawak. The
Malaysian Journal of Analytical Sciences, 16(1): 1 - 11.
27. Law, A.T., Ravinthar, V. &
Yeong, C.H. (1990). Oil pollution in the coastal waters off Port Dickson,
Straits of Malacca. Pertanika, 13: 381-387.
28. Abdullah A.R.
& Samah, A.A. (1996). Oil and grease in coastal waters. In: Oil and grease
pollution in the Malaysian marine environment. A.R. Abdullah and C.W. Wang
(ed.), Department of Environment, Malaysia.
29. Tahir, N.M., Abdullah, A.R.
& Shanmugam, S. (1997). Determination of total hydrocarbon concentration in
coastal waters and sediments off the east coast of Peninsular Malaysia. Environmental Geochemistry and Health, 19: 67-71.
30. Abdullah, M. P. (1997).
Hydrocarbon pollution in the sediment of some Malaysian coastal areas. Environmental Monitoring and Assessment,
44: 443-454.
31. Siti Aishah Mohd Ali, Rohana Tair, Soon Zhi Yang & Masni Mohd Ali.
(2013). Petroleum hydrocarbon in surface sediment from coastal area of Putatan
and Papar, Sabah. The Malaysian Journal
of Analytical Sciences, 17(2): 286-290.
32. Rudolf, J., Ahmed, I.R., Medeiros,
P.M. & Bernd, R.T.S. (2006). Natural product biomarkers as indicators of sources
and transport of
sedimentary organic matter in a subtropical river. Chemosphere, 64: 18701884.