Malaysian Journal of Analytical Sciences Vol 19 No 4 (2015): 766 - 774

 

 

 

NATURAL RADIONUCLIDES AND HEAVY METALS POLLUTION IN SEAWATER AT KUALA LANGAT COASTAL AREA

 

(Pencemaran Radionuklid Semulajadi dan Logam Berat di dalam Air Laut di Kawasan Persisiran Pantai Kuala Langat)

 

Sabarina Md Yunus* Zaini Hamzah, Ab Khalik Hj Wood, Ahmad Saat

 

Faculty of Applied Sciences,

Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

 

*Corresponding author: sabarina2020@salam.uitm.edu.my

 

 

Received: 23 November 2014; Accepted: 27 June 2015

 

 

Abstract

Rapid industrial developments along the Langat river basin play an important role in contributing to the increases of pollution loading at Kuala Langat coastal area. The major pollutant sources in this area may be originating from human activities such as industrial discharge, domestic sewage, construction, agriculture and pig farming near the tributaries that affects the water quality. In addition, Langat and Semenyih rivers flow through the mining and ex-mining area, which is related to the source of natural radionuclides contamination.  Heavy metals in the aquatic environment and more likely to enter the food chain. This study is focusing to the levels of radionuclides and heavy metals in seawater. The samples were collected using appropriate water sampler, which is then acidified until pH 2 and filtered using cellulose acetate 0.45 μm.  The concentration of these radionuclides and heavy metals were determined using Inductive Coupled Plasma Mass Spectrometer (ICPMS) after dilution. In general, the radionuclides and heavy metals concentrations are lower than Malaysia Marine Water Quality Standard (MMWQS) except for few locations where the concentration levels above the standards. The higher concentration of pollutant in the seawater may have a toxic effect on sensitive plants and living organisms. The results of pollution levels of these radionuclides and heavy metals were also compared with other studies.

 

Keywords: heavy metals, pollution, radionuclides, uranium, thorium

 

Abstrak

Perkembangan perindustrian yang pesat di sepanjang lembangan Sungai Langat memainkan peranan yang penting dalam menyumbang kepada peningkatan beban pencemaran di kawasan pantai Kuala Langat. Sumber pencemar utama di kawasan ini terdiri daripada aktiviti manusia seperti pelepasan industri, kumbahan domestik, pembinaan, pertanian dan penternakan babi berhampiran anak sungai yang menjejaskan kualiti air. Di samping itu, Sungai Langat dan Semenyih mengalir melalui kawasan perlombongan dan bekas lombong yang berkaitan dengan punca pencemaran radionuklid semula jadi. Logam berat dalam persekitaran akuatik lebih cenderung untuk memasuki rantai makanan. Kajian ini memberi tumpuan kepada tahap radionuklid dan logam berat dalam air laut. Sampel telah dikumpulkan menggunakan sampler air yang sesuai, yang kemudiannya diasidkan sehingga pH 2 dan ditapis menggunakan selulosa asetat 0.45 μm. Kepekatan radionuklid dan logam berat telah ditentukan menggunakan plasma induktif spektrometer jisim (ICPMS) selepas pencairan. Secara umum, radionuklid dan kepekatan logam berat adalah lebih rendah daripada Malaysia Standard Kualiti Air Marin (MMWQS) kecuali di beberapa lokasi di mana tahap kepekatan di atas piawaian. Kepekatan yang tinggi bahan pencemar dalam air laut yang mungkin mempunyai kesan toksik pada tanaman yang sensitif dan organisma hidup. Keputusan tahap pencemaran ini radionuklid dan logam berat juga dibandingkan dengan kajian-kajian lain.

 

Kata kunci: logam berat, pencemaran, radionuklid, uranium, thorium

 

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