Sains Malaysiana 38(3): 359-364(2009)
Electrochemical impedance spectroscopy and Surface Studies of Steel
Corrosion by Sulphate-Reducing Bacteria
(Kajian Spektroskopi Impedans Elektrokimia dan Permukaan
Terhadap Kakisan Keluli oleh Bakteria Penurun-Sulfat)
Fathul Karim Sahrani1*, Zaharah Ibrahim2, Madzlan Aziz3 & Adibah Yahya2
1Marine Ecosystem Research Centre (EKOMAR), Faculty of Science and Technology
Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor, Malaysia
2Deparment of Biology Industry, Faculty of Bioscience and Bioengineering
Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
3Department of Chemistry, Faculty of Science,
Universiti Teknologi Malaysia, 81310 UTM Skudai, Johor, Malaysia
Diserahkan: 17 April 2008 / Diterima: 29 April 2008
ABSTRACT
Sulphate-reducing
bacteria (SRB), implicated in microbiologically influenced corrosion were
isolated from the deep subsurface at the vicinity of Pasir Gudang, Johor,
Malaysia. Electrochemical impedance spectroscopic (EIS) study was carried out
to determine the polarization resistance in various types of culturing
solutions, with SRB1, SRB2, combination of SRB1 and SRB2 and without SRBs
inoculated (control). EIS results showed
that in the presence of SRB1, SRB2 and
mixed culture SRB1 and SRB2, polarisation resistance values were 7170, 6370 and
7190 ohms respectively compared to that of control, 92400 ohm. X-ray analysis (EDS)
of the specimens indicated high sulphur content in the medium containing SRBs. Localized
corrosion was observed on the metal surface which was associated with the SRB
activity.
Keywords: Electrochemical impedance spectroscopy; microbiologically
influenced corrosion; sulphate-reducing
bacteria
ABSTRAK
Bakteria
penurun-sulfat, memberi kesan kepada kakisan yang dipengaruhi oleh mikrobiologi
telah dipencilkan dari dasar persekitaran Pasir Gudang, Johor, Malaysia.
Spektroskopi impedans elektrokimia telah digunakan bagi menentukan rintangan
pengutuban dalam pelbagai larutan kultur iaitu SRB1, SRB2, gabungan SRB1 dan
SRB2 dan tanpa SRB (kawalan). Keputusan EIS menunjukkan dengan kehadiran SRB1,
SRB2 dan kultur campuran SRB1 dan SRB2, rintangan pengutuban masing-masing ialah
7170, 6370 dan 7190 ohm, berbanding dengan kawalan 92400 ohm. Analisis sinar-x
(EDS) terhadap spesimen menunjukkan kandungan sulfur yang tinggi dalam medium
yang mengandungi SRB. Kakisan setempat diperhatikan berlaku dan mempunyai
kaitan dengan aktiviti SRB.
Kata kunci: Bakteria
penurun sulfar; hakisan dipengaruhi mikrobiologi; spektroskopi impedans
elektrokimia
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*Pengarang untuk surat-menyurat; email: fathul@ukm.my
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