Sains Malaysiana 40(3)(2011): 215–219
Synthesis of Polyaniline-Montmorillonite Nanocomposites Using H2O2 as
the Oxidant
(Sintesis Komposit Nanopolianilia-Montmorilonit Menggunakan H2O2 sebagai Pengoksida)
Narayanan Binitha*,1,2, Viswanathan Suraja2, Zahira Yaakob2 & Sankaran Sugunan3
1Department of
Chemistry
Sree Neelakanta Government Sanskrit College, Pattambi,
Kerala, India
2Department of
Chemical and Process Engineering
Faculty of Engineering and Built
Environment, Universiti Kebangsaan Malaysia
43600, Bangi,
Selangor, D.E., Malaysia
3Department of
Applied Chemistry
Cochin University of Science and
Technology, Cochin, Kerala, India
Diserahkan: 22 Julai 2010 / Diterima: 3
September 2010
ABSTRACT
Polyaniline montmorillonite nanocomposite was
prepared using H2O2 as
the oxidant. The catalytic environment of montmorillonite favours polymerization. Intercalation and composite
formation was proven from various techniques such as XRD, FTIR, DRS and thermal analysis. XRD patterns give the dimension
of the intercalated PANI, from the shift of 2θ
values, which is in the nano range. FTIR showed
that PANI composite formation occured without affecting the basic clay layer structure. Thus the successful
development of an alternative cheap route for polyaniline–montmorillonite nanocomposite was well established.
Keywords: Chemical
synthesis; montmorillonite; polyaniline nanocomposite
ABSTRAK
Komposit nanopolianilin-montmorilonit telah disediakan dengan menggunakan H2O2 sebagai pengoksida. Montmorilonit bersifat pemangkin yang dapat membantu pempolimeran. Kemasukan dan pembentukan komposit telah dibuktikan melalui berbagai ujian seperti XRD, FTIR, DRS and analisis terma. Corak ujian XRD membuktikan adanya kemasukan PANI yang dapat dilihat melalui perubahan nilai 2θ, yang merupakan julat nano. Ujian FTIR menunjukkan pembentukan komposit PANI terjadi tanpa mengganggu struktur asas lapisan tanah liat. Kajian ini telah menghasilkan kaedah alternatif untuk menghasilkan komposit nano polianilia–montmorilonit dengan kos yang rendah.
Kata kunci: Komposit nanopolianilia; montmorilonit; sintesis kimia
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*Pengarang untuk surat-menyurat; email:
binithann@yahoo.co.in
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