Sains Malaysiana 46(4)(2017):
615–621
http://dx.doi.org/10.17576/jsm-2017-4604-14
Rapid Extraction of Bisphenol
A by Dispersive Liquid-Liquid Microextraction based on Solidification
of Floating Organic
(Pengekstrakan Pantas
Bisfenol A dengan Pengekstrakan Mikro Cecair-Cecair Serakan berdasarkan
Pemejalan Organik Terapung)
SAW HONG
LOH1,2*,
SHAN
TEIK
ONG1,
MEE
LIN
NGU1
& MARINAH MOHD ARIFFIN1
1School of Marine and
Environmental Sciences, Universiti Malaysia Terengganu
21030 Kuala Terengganu,
Terengganu Darul Iman, Malaysia
2Institute of Marine Biotechnology,
Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu
Darul Iman, Malaysia
Diserahkan: 16 Februari
2016/Diterima: 21 September 2016
ABSTRACT
Bisphenol A is an endocrine
disruptor with widespread applications, especially in the production
of polycarbonate and epoxy resins. Dispersive liquid-liquid microextraction
based on solidification of floating organic technique has been developed
for the extraction of bisphenol A from water and soft drink. The
1-undecanol has been applied as the extraction solvent because of
its low density and melting point and high affinity to the analyte.
The technique offered rapid and simple analysis as the 1-undecanol
was homogeneously dispersed in the sample solution to speed the
extraction and the collection of extraction solvent was simplified
by centrifugation, cooling and melting steps.
Keywords: Bisphenol
A; dispersive liquid-liquid microextraction based on solidification
of floating organic; high performance liquid chromatography-fluorescence
detection; water
ABSTRAK
Bisfenol A ialah suatu
pengganggu endokrin yang mempunyai aplikasi meluas, khususnya dalam
pengeluaran polikarbonat dan resin epoksi. Teknik pengekstrakan
mikro cecair-cecair serakan berdasarkan pemejalan organik terapung
telah dibangunkan untuk mengekstrak bisfenol A daripada air dan
minuman ringan. 1-undekanol telah digunakan sebagai pelarut pengekstrakan
disebabkan ketumpatan dan takat leburnya yang rendah dan tarikannya
yang kuat terhadap analit. Teknik ini menawarkan analisis yang pantas
dan senang kerana 1-undekanol menyerak dengan homogen di dalam larutan
sampel untuk mempercepatkan pengekstrakan dan pengumpulan pelarut
pengekstrakan telah dipermudahkan melalui langkah pengemparan, penyejukan
dan peleburan.
Kata kunci: Air; bisfenol
A; kromatografi cecair prestasi tinggi-pengesanan pendarfluor; pengekstrakan
mikro cecair-cecair serakan berdasarkan pemejalan organik terapung
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*Pengarang
untuk surat-menyurat; email: lohsh@umt.edu.my
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