Sains Malaysiana 47(11)(2018): 2887–2897
http://dx.doi.org/10.17576/jsm-2018-4711-32
Potential of Membrane Technology for Treatment
and Reuse of Water from Old Mining Lakes
(Potensi Teknologi Membran untuk Rawatan
dan Penggunaan Semula Air dari Tasik Lombong Lama)
TEOW YEIT
HAAN1,2*,
ABDUL
WAHAB
MOHAMMAD1,2,
SYAZAMAN
RAMLI2,
MOHD
SHAIFUL
SAJAB1,2
& NOORINI
IZZATI
MOHAMAD
MAZUKI2
1Research Centre for Sustainable
Process Technology (CESPRO), Faculty of Engineering and Built
Environment, Universiti Kebangsaan Malaysia, 43600 UKM Bangi,
Selangor Darul Ehsan, Malaysia
2Chemical Engineering Programme,
Faculty of Engineering and Built Environment, Universiti Kebangsaan
Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia
Received:
22 May 2018 /Accepted: 22 July 2018
ABSTRACT
The El-Nino phenomenon in early
2014 contributed to the lack of water supply in most Southeast
Asian countries. Suggestions have since been made to ensure the
continuity of water supply, one of which involves membrane technology
to treat mine water so that it is compatible for citizens’ use.
Accordingly, the objective of this research was to study the efficiency
of membrane technology in treating mine water. Our elucidation
of all the parameters has showed that the best attainable classification
is at Class IV. Although it was still regarded as polluted, the
treated mine water can be used as water supply reservoir. For
the membranes tested such as ultrafiltration 10 kDa, 5 kDa and
reverse osmosis, the percentage of rejection for chemical oxygen
demand is 21-72%, 40-96% for total suspended solids and 21-72%
for ammonia nitrogen. The pH also gradually shifted to almost
neutral after the filtration.
Keywords: Heavy metal; mine
water; membrane technology; water quality parameter; water reuse
ABSTRAK
Fenomenon cuaca El-Nino pada
awal 2014 menyumbang kepada kekurangan bekalan air di kebanyakan
negara di Asia Tenggara. Objektif kajian ini adalah untuk mengkaji
kecekapan teknologi membran untuk rawatan air lombong dengan membandingkan
parameter kualiti air sebelum dan selepas penurasan berdasarkan
Indeks Kualiti Air (WQI)
seterusnya memberi cadangan reka bentuk loji rawatan air yang
merawat air lombong dengan menggunakan teknologi membran. Semua
parameter yang dikaji menunjukkan bahawa klasifikasi maksimum
yang tercapai adalah Kelas IV. Berdasarkan WQI,
walaupun semua air lombong dianggap tercemar tetapi ia masih dapat
digunakan sebagai sumber air takungan. Nilai WQI yang berada dalam lingkungan
47-65 dikategorikan sebagai Kelas III dan IV. Untuk membran yang
diuji seperti penurasan ultra 10 kDa, 5 kDa dan osmosis songsang,
peratusan penolakan untuk permintaan oksigen kimia adalah 21-72%,
40-96% untuk jumlah pepejal terampai dan 21-72% untuk nitrogen
ammonia. pH juga beransur-ansur berubah hampir ke neutral selepas
proses penurasan dijalankan.
Kata kunci: Air lombong; logam berat; parameter kualiti air; penggunaan
semula air; teknologi membran
REFERENCES
Baird, R.B., Eaton,
A.D. & Clesceri, L.S. 2012. Standard Methods for the Examination
of Water and Wastewater. Location: American Water Works Association.
Bernal, M.P. &
McGrath, S.P. 1994. Effects of pH and heavy metal concentrations
in solution culture on the proton release, growth, and element
composition of Alyssum murale and Raphanus sativus L.
Plant and Soil 166: 83-92.
Brake Perry, F.
1998. Supplemental Guidance for the Determination of Biochemical
Oxygen Demand (BODs) and Carbonaceous BOD (CBODs) in Water and
Wastewater. Washington State Department of Ecology Environmental
Assessment Program. Lab Accreditation Section. Publication No.
98-307.
Department of Environment
Malaysia (DOE). 2008. Interim
National Water Quality Standard for Malaysia. http://www.
doe.gov.my/index.php?option=comContent&task=view&id =244&Itemid=615&lang=en.
Accessed on August 19, 2015.
Department of Statistics
Malaysia. 2014. Statistic at Selangor. https://www.statistics.gov.my.
Accessed on June 8, 2015.
Field, R. 2010.
Fundamentals of fouling, in membrane technology. In Membranes
for Water Treatment, Volume 4, edited by Peinemann, K.V. &
Nunes, S.P. Weinheim: Wiley- VCH Verlag GmbH & Co. KgaA.
GEA Filtration.
2010. Membrane Filtration
Process. http://www. geafiltration.com/technology/technology.asp.
Accessed on August 16, 2015.
Georgescu, D.P.
& Anderi, L. 2000. Treatment of tailings water from uranium
ore processing by reverse osmosis. Uranium 2000: International
Symposium on the Process Metallurgy of Uranium 35(43): 9-15.
Hassan, W.F.W.
& Purwanto, H.S. 2003. Analisis bendalir terkepung pada Telerang
Kuarza, Kuala Lipis dan Lubok Mandi, Terengganu, Semenanjung Malaysia.
Bulletin of the Geological Society of Malaysia 46: 359-363.
Hydranautics. 2001.
Design Parameters Affecting
Performance. https://www.google.com/url?sa=t&rct=j&q=&esrc=s&sourc
e=web&cd=2&ved=0CCwQFjABahUKEwjgvfuAia3HAhVFC44KHarkARY&url=http%3A%2F%2Fwww.membranes.
com%2Fdocs%2Ftrc%2Fdesparam.pdf&ei=dzrQVaCmEsW WuASqyYewAQ&usg=AFQjCNHVoRdQBmMH3i5e2fG9JoioIQuWew&bvm=bv.99804247,d.c2E&cad=rja.
Accessed on August 16, 2015.
Jabatan Alam Sekitar.
2010. Malaysia Environment Quality Report.
Kesieme, U.K. & Aral, H. 2015.
Application of membrane distillation and solvent extraction for
water and acid recovery from acidic mining waste and process solutions.
Journal of Environmental Chemical Engineering 3(3): 2050-2056.
Mullett, M., Fornarelli, R. &
Ralph, D. 2014. Nanofiltration of mine water: Impact of feed pH
and membrane charge on resource recovery and water discharge.
Membranes 4(2): 163-180.
Nanda, D., Tung, K.L., Li, Y.L.,
Lin, N.J. & Chuang, C.J. 2010. Effect of pH on membrane morphology,
fouling potential, and filtration performance of nanofiltration
membrane for water softening. Journal of Membrane Science 349:
411-420.
Rozkowski, A. & Rozkowski, J.
1994. Impact of mine waters on river water quality in the upper
Silesian Coal Basin. 5th International Mine Water Congress,
Nottingham (U.K.). pp. 811- 821.
Sivakumar, M., Morton, S.G.S. &
Singh, R.N. 1994. Case history analysis of mine water pollution
in New South Wales, Australia. 5th International Mine Water
Congress, Nottingham (U.K.). pp. 823- 834.
Suruhanjaya Perkhidmatan Air Negara.
2013. Jumlah Penggunaan Air (2009-2010). http://www.span.gov.my.html.
Accessed on 5 May 2015.
Wilmoth, R.C., Baugh, T.L. &
Decker, D.W. 1978. Removal of selected trace elements from acid
mine drainage using existing technology. 33rd Industrial Waste
Conference. pp. 886-894.
*Corresponding author;
email: yh_teow@ukm.edu.my