The Malaysian Journal of Analytical Sciences Vol 10 No 1 (2006): 1 – 6

 

 

 

TREATMENT OF LANDFILL LEACHATE IN KAYU MADANG, SARAH: TEXTURAL AND PHYSICAL CHARACTERIZATION (PART 1)

 

Coffin G. Joseph, Hasnuf Fazfi Md. Zain, & Siti Fatimah Dek

 

Industrial Chemistry Program, School of Science & Technology,

Universiti Malaysia Sabah, 88999 Kota Kinabalu, Sabah

 

Abstract

Activated carbons from two agro-industrial wastes; oil palm shells (OPS) and coconut husk (CH); were prepared by chemical activation using potassium hydroxide as the dehydrating agent. A two- stage process was used; with semi-carbonization stage at 200oC for 15 minutes as the first stage followed by an  activation  stage  at  500oC  for  45  minutes  as  the  second  stage.  The  precursor  material  with  the impregnation agent was exposed straightaway to semi-carbonization and activation temperature unlike the specific  temperature  progression  as  reported  in  the  literature.  All  experiments  were  conducted  in  a laboratory scale muffle furnace under static conditions in a self generated atmosphere. We found that by using this method, the OPS prepared with the KOH   impregnation ratio of 25% had the highest Iodine Number which was 466.1mg/g but CH with the similar impregnation ratio had the highest Methylene Blue adsorption capacity  and percentage of yield, which were 10.9mg/g and 74.68% respectively.

 

Keywords: activated carbons; two-stage activation process, physical and chemical properties

 

Reference

1.    Anuar, K., Collin, G. J., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan Abdullah, A. H. (2003) “Surface area and porosity  studies  of  activated  carbons  prepared  from  oil  palm  shells  (Elaeis  Guineensis)  using  physical  and chemical activators such as CO2, H3PO4, K3PO4  and KOH” ASEAN J. of Sci. And Tech. For Dev., 20(2), 149-158.

2.     Anuar, K., Collin, G. J., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan  Abdullah, A. H. (2004) “Activated carbons prepared from oil palm shells :  application for column separation of heavy metals”  Indian Chem. Soc., 81(12), 946-949.

3.     Anuar, K., Collin, G. J., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan  Abdullah, A. H. (2002) “Preparation and characterization  of  activated  carbon  from  Resak  wood  (Vatica  Hullettii):  surface  area  and  porosity  studies” Oriental J. of  Chem., , 18(1), 43-46.

4.     Anuar, K., Collin, G. J., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan Abdullah, A. H. (2001) “ Preparation and characterizations of activated carbon  from Resak wood (Vatica Hullettii)“ Res. J. of  Chem.Environ., 5(3), 21-24.

5.     Gergova, K., Petrov, N., Eser, S. (1994) “Adsorption properties and microstructure of activated carbons produced from agricultural by-products by steam pyrolysis”  Carbon, 32, 693-702.

6.     Marsh, H., Crawford, T.M., O’Grady, T.M., Wennerberg, A.N. (1982) “Carbons of high surface area. A study by adsorption and high resolution electron microscopy”  Carbon, 20, 419-426.

7.     O’Grady, T.M., Wennerberg, A.N. (1986) Petroleum-Derived Carbons, High-Surface-Area Active Carbon, in: ACS Symposium Series, 303, American Chemical  Society, 302.

8.     Otawa, T., Nojima, Y., Miyazaki, T. (1997), “Development of KOH activated high surface area  carbon and its application to drinking water purification” Carbon, , 35,   1315-1319.

9.     Otawa, T., Tanibata, R., Itoh, M. (1993) “Production and adsorption characteristics  of MAXSORB: High-surface-area active carbon” Gas Sep. Purif., 7, 241-245.

10.  Ahmadpour, A., Do, D.D., (1996) “The preparation of active carbons from coal   by  chemical  and physical activation” Carbon, 34, 471-479.

11. Ahmadpour, A., Do, D.D. (1997) “The preparation of activated carbon from macadamia nutshell  by chemical activation”  Carbon, , 35, 1723-1732.

12. Hu, Z.H., Vansant, E.F. (1995) “Chemical activation of elutrilithe producing   carbon-aluminosilicate  composite adsorbent” Carbon, 33, 1293-1300.

13. Laine, J., Calafat, A. (1991) “Factors affecting the preparation of activated carbons from coconut shell catalized by potassium”  Carbon, 29, 949-953.

14.  Hu,  Z.H.,  Srinivasan,  M.P.  (1999)  “Preparation  of  high-surface-area  activated  carbons  from  coconut  shell” Micropor. Mesopor. Mater. 27, 11-18.

15. Kirubakaran, J.C., Krishnaiah, K., Sheshadri, S.K. (1991) Ind. And Eng. Chem. Res., 30, 2411.

16. Toles, C. A., Marshall, W.E., Johns M.M.( 1998) J. Chem. Tech., 72, 255

17. Dastgeib S.A., Rockstraw D.A. (2001) “Pecan shell activated carbon: synthesis, characterization, and application for the removal of copper from aqueous  solution” Carbon, 39, 1849-1855.

18. Lafi W.K. (2001) “Production of activated carbon from acorns and olive seeds” Biomass and Bioenergy, 20, 57-62.

19. SIRIM (1984). Specification of powdered activated carbon MS 873: Standard and   Industrial  Research Institute Malaysia.

20. Kirkaldy, J.L.R., Sutanto, J.B. (1976) Planter Kuala Lumpur, 52, 118.

21. Wigmans, T. (1989) “Industrial aspects of production and use of activated  carbons” Carbon, 27, 13-22.

22.  Lamond,  T.G.,  Marsh,  H.  (1963)  “The  surface  properties  of  carbon—III  the      process  of   activation  of carbons” Carbon, 1, 293-302.

23. Chan, K.C., Goh, S.H., Ing, T.W. (1976) Planter Kuala Lumpur, 52, 127

24. Fong, A.W., (1999) Panduan Penanaman Kelapa, Jabatan Pertanian Sabah. No. 112/IC/1999.

25. Jankowska, H., Swiatkowski, and Choma, (1991) J., Active Carbon, Elis Horwood Ltd.

26. Anuar, K., Collin, G. J., Dzulkefly, K., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan   Abdullah,  A. H. and Jamaluddin   D.(2004)   “Activated   carbons   from   oil                palm   shells   (Elaeis   Guineensis)-preparation   and characterization”  Mal. J. Of  Anal. Sci., 8(1), 130-134.

27. Collin G. Joseph, Fauziah Hj. Abdul Aziz, Hasnul Fazli Md. Zain, dan Siti Fatimah Dek, 2005,  Treatment of Landfill Leachate In Kayu Madang, Sabah: Porosity and Adsorption Studies (Part 2), Asian Chem. Letters, 10(3), (in press).

 




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