The
Malaysian Journal of Analytical Sciences Vol 10 No 1 (2006): 1 – 6
TREATMENT OF
LANDFILL LEACHATE IN KAYU MADANG, SARAH:
TEXTURAL AND PHYSICAL CHARACTERIZATION
(PART 1)
Coffin G. Joseph, Hasnuf
Fazfi Md. Zain, & Siti Fatimah Dek
Industrial Chemistry Program,
School of Science & Technology,
Universiti Malaysia
Sabah, 88999 Kota Kinabalu, Sabah
Abstract
Activated carbons
from two agro-industrial wastes; oil palm shells (OPS) and coconut husk (CH); were
prepared by chemical activation using potassium hydroxide as the dehydrating agent.
A two- stage process was used; with semi-carbonization stage at 200oC
for 15 minutes as the first stage followed by an activation stage at
500oC for 45
minutes as the second stage.
The precursor material with the
impregnation agent was exposed straightaway to semi-carbonization and activation
temperature unlike the specific temperature
progression as reported
in the literature.
All experiments were conducted
in
a laboratory scale muffle furnace under static conditions in a self generated
atmosphere. We found that by using this method, the OPS prepared with the KOH impregnation ratio of 25% had the highest Iodine
Number which was 466.1mg/g but CH with the similar impregnation ratio had the highest
Methylene Blue adsorption capacity and percentage
of yield, which were 10.9mg/g and 74.68% respectively.
Keywords: activated carbons;
two-stage activation process, physical
and chemical properties
Reference
1. Anuar, K., Collin,
G. J., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan Abdullah, A. H. (2003) “Surface
area and porosity studies of activated
carbons prepared from oil
palm shells (Elaeis
Guineensis) using physical
and chemical activators such as CO2, H3PO4,
K3PO4 and KOH” ASEAN J. of Sci. And Tech.
For Dev., 20(2), 149-158.
2.
Anuar, K., Collin, G. J., Zulkarnain, Z.,
Hussein, M. Z., Haron, M.J. dan Abdullah,
A. H. (2004) “Activated carbons prepared from oil palm shells : application for column separation of heavy metals”
Indian Chem. Soc., 81(12), 946-949.
3. Anuar, K., Collin, G. J., Zulkarnain, Z., Hussein,
M. Z., Haron, M.J. dan Abdullah, A. H.
(2002) “Preparation and characterization of
activated carbon from
Resak wood (Vatica
Hullettii): surface area
and porosity studies” Oriental J. of Chem., , 18(1), 43-46.
4.
Anuar, K., Collin, G. J., Zulkarnain, Z.,
Hussein, M. Z., Haron, M.J. dan Abdullah, A. H. (2001) “ Preparation and characterizations
of activated carbon from Resak wood (Vatica
Hullettii)“ Res. J. of Chem.Environ., 5(3),
21-24.
5.
Gergova, K., Petrov, N., Eser, S. (1994)
“Adsorption properties and microstructure of activated carbons produced from agricultural
by-products by steam pyrolysis” Carbon,
32, 693-702.
6. Marsh, H., Crawford, T.M., O’Grady, T.M., Wennerberg,
A.N. (1982) “Carbons of high surface area. A study by adsorption and high resolution
electron microscopy” Carbon, 20, 419-426.
7.
O’Grady, T.M., Wennerberg, A.N. (1986)
Petroleum-Derived Carbons, High-Surface-Area Active Carbon, in: ACS Symposium Series,
303, American Chemical Society, 302.
8. Otawa, T., Nojima, Y., Miyazaki, T. (1997), “Development
of KOH activated high surface area carbon
and its application to drinking water purification” Carbon, , 35, 1315-1319.
9.
Otawa, T., Tanibata, R., Itoh, M. (1993)
“Production and adsorption characteristics of MAXSORB: High-surface-area active carbon” Gas
Sep. Purif., 7, 241-245.
10.
Ahmadpour, A., Do, D.D., (1996) “The preparation
of active carbons from coal by
chemical and physical activation”
Carbon, 34, 471-479.
11. Ahmadpour, A., Do, D.D. (1997) “The preparation
of activated carbon from macadamia nutshell by chemical activation” Carbon, , 35, 1723-1732.
12. Hu,
Z.H., Vansant, E.F. (1995) “Chemical activation of elutrilithe producing carbon-aluminosilicate
composite adsorbent” Carbon, 33, 1293-1300.
13.
Laine, J., Calafat, A. (1991) “Factors affecting the preparation of activated
carbons from coconut shell catalized by potassium” Carbon, 29, 949-953.
14. Hu, Z.H.,
Srinivasan, M.P. (1999)
“Preparation of
high-surface-area activated carbons from coconut
shell” Micropor. Mesopor. Mater. 27,
11-18.
15.
Kirubakaran, J.C., Krishnaiah, K., Sheshadri, S.K. (1991) Ind. And Eng. Chem.
Res., 30, 2411.
16.
Toles, C. A., Marshall, W.E., Johns M.M.(
1998) J. Chem. Tech., 72, 255
17. Dastgeib
S.A., Rockstraw D.A. (2001) “Pecan shell activated carbon: synthesis, characterization,
and application for the removal of copper from aqueous solution” Carbon, 39, 1849-1855.
18.
Lafi W.K. (2001) “Production of activated
carbon from acorns and olive seeds” Biomass and Bioenergy, 20, 57-62.
19. SIRIM
(1984). Specification of powdered activated carbon MS 873: Standard and Industrial
Research Institute Malaysia.
20.
Kirkaldy, J.L.R., Sutanto, J.B. (1976) Planter Kuala Lumpur, 52, 118.
21.
Wigmans, T. (1989) “Industrial aspects of production and use of activated carbons” Carbon, 27, 13-22.
22.
Lamond, T.G., Marsh,
H. (1963) “The
surface properties of carbon—III
the process
of
activation of carbons” Carbon, 1, 293-302.
23.
Chan, K.C., Goh, S.H., Ing, T.W. (1976) Planter Kuala Lumpur, 52, 127
24.
Fong, A.W., (1999) Panduan Penanaman Kelapa, Jabatan Pertanian Sabah. No. 112/IC/1999.
25.
Jankowska, H., Swiatkowski, and Choma, (1991) J., Active Carbon, Elis Horwood
Ltd.
26. Anuar,
K., Collin, G. J., Dzulkefly, K., Zulkarnain, Z., Hussein, M. Z., Haron, M.J. dan Abdullah,
A. H. and Jamaluddin D.(2004) “Activated carbons from oil palm shells (Elaeis Guineensis)-preparation and characterization”
Mal. J. Of Anal. Sci., 8(1), 130-134.
27. Collin
G. Joseph, Fauziah Hj. Abdul Aziz, Hasnul Fazli Md. Zain, dan Siti Fatimah Dek,
2005, Treatment of Landfill Leachate In Kayu
Madang, Sabah: Porosity and Adsorption Studies (Part 2), Asian Chem. Letters,
10(3), (in press).