The
Malaysian Journal of Analytical Sciences Vol 11 No 1 (2007): 206 – 212
COMPARISON STUDIES ON SODA LIGNIN AND SODA-
ANTHRAQUINONE LIGNIN
M. N. Mohamad Ibrahim, N. N. Mohamad Yusof and A.
Hashim
School of
Chemical Sciences, Universiti Sains Malaysia,
11800 Minden,
Pulau Pinang, Malaysia
Abstract
Soda
lignin and soda anthraquinone lignin were compared in this study. The
physico-chemical properties and structural features of the isolated lignin were
characterized by Fourier Transform Infrared Spectroscopy (FTIR), Ultraviolet
(UV), ash test, Carbon-Hydrogen-Nitrogen (CHN) analyzer, Nuclear Magnetic
Resonance (13C-NMR) and High Performance Liquid Chromatography
(HPLC). Nitrobenzene oxidation was performed
on these two types of lignin especially for the HPLC analysis. Based on
the CHN, 13C-NMR and UV results there were no significant
differences between soda lignin and soda anthraquinone lignin. The FTIR results
also showed that there were no significant differences in terms of functional
groups
that
exist in both lignin.
Keywords: Oil palm empty fruit
bunches fibers, black liquor, soda lignin, soda anthraquinone lignin
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