The
Malaysian Journal of Analytical Sciences Vol 11 No 1 (2007): 280 – 286
DETERMINATION OF HEAVY METALS CONTENT IN SOILS AND
INDOOR DUSTS FROM NURSERIES IN DUNGUN, TERENGGANU
Norhayati Mohd Tahir*, Poh Seng Chee and Maisarah
Jaafar
Environmental
Research Group, Department of Chemical Sciences,
Faculty of
Science and Technology, Universiti Malaysia Terengganu, Mengabang Telipot,
21030 Kuala
Terengganu, Terengganu
*Corresponding
author: hayati@umt.edu.my
Abstract
Concentrations
of Cu, Mn, Cd, Pb, Zn, Fe and Al in indoor dusts and outdoor soils from
nurseries located in industrial, town and village area of Dungun district were determined by
Atomic Absorption Spectroscopy (AAS)
following the acid digestion of the respective soil and indoor dust sample. The
range of metals observed in soils were 0.46-46.9 µg/g, 23.2-338 µg/g, below
detection limit (BDL) -4.66 µg/g, 2.26-130 µg/g, BDL-91.7 µg/g and 5310-114000
µg/g, for Cu, Mn, Cd, Zn, Pb and Al
respectively. Although the
results showed a relatively low contamination in general, the village areas had appreciably
higher level of toxic metals compared to both town and industrial areas for outdoor soils.
Atmospheric depositions and the distance from the main roadside appeared to
have an influence on the Pb distribution in soils. Industrial areas on the
other hand exhibited higher mean concentration of Cu, Mn, Fe, Pb and Zn in
their indoor dust compared to town and village areas . Evaluation of enrichment factors suggest that possible
sources of Cu, Mn and Zn in indoor dusts could be from internal source.
Keywords : soil, indoor
dust, heavy metals, Dungun, nurseries.
References
1. Charlesworth S., Everett M., McCarthy
R., Ordonez A. and de Miguel E. (2003). Comparative study of heavy metal
concentration and distribution in deposited street dusts in a large and a small
urban area: Birmingham and Coventry, West Midlands, United Kingdom. Environment
International 29:563-573.
2. Lee C.S.L., Li X.D., Shi W.Z.,
Cheung S.C. and Thornton I. (2006).
Metal contamination in urban, sub-urban,
and country park soils of Hong Kong: A study based on GIS and multivariate
statistics. Science of the Total Environment, 356:45-61.
3. Yang Y., Campbell C.D., Clark L., Cameron C.M. and Paterson E..
(2006). Microbial indicators of heavy
metal contamination in urban and rural soils. Chemosphere 63: 1942-1952.
4. Komarnicki G.J.K. (2005). Lead and cadmium in indoor air and the urban
environment. Environmental Pollution, 136:47-61.
5. Othman A.F. and Ghandour M.A. (2005).
Square-wave stripping voltammetry for direct determination of eight heavy
metals in soil and indoor-airborne particulate matter. Environment Research,
97:229-235.
6. Srivastava A. and Jain V.K. (2007). A
study to characterize the suspended particulate matter in an indoor environment
in Delhi, India. Building and Environment, 42:2046-2052.
7. Ross D. (1995). Recommended methods for
determining soil cation exchange capacity. Page 62-70 in Recommended soil
testing procedures for the Northeastern United States, 2nd edition, eds. by J. T. Sims and A. Wolf, Pennsylvania.
8. Ren H.M., Wang J.D. and Zhang X.L. (2005). Assessment of soil lead exposure in
children in Shenyang, China. Environment
al Pollution, 144:327-335.
9. Mielke H.W., Berry K.J., M ielke P.W., Powell E.T., and
Gonzales C.R. (2005). Multiple metal accumulations as a factor in learning
achievement within various New Orleans elementary school communities.
Environmental Research, 97:67-75.
10. Ljung
K., Selinus O. and Otabbong E. (2006). Metals in soils of children’s urban
environments in the small northern European city of Uppsala. Science of the
Total Environment, 366:749-759.
11. Ure
A.M. and Berrow M.L. (1982). The elemental constituents of soils. The Royal
Society of Chemistry, London. Pages 203-204.
12. Al-Rajhl
M.A. and Seaward M .R.D. (1996) Metal levels in indoor and outdoor
dust in Rtyadh, Saudi Arabia. Environmental
International 22:315-324.
13. Tong
S.T.Y. and Lam K.C. (1998). Are nursery schools and kindergartens safe for our
kids? The Hong Kong study. The Science of the Total Environment 216:217-225.
14. Jaradat
Q.M., Momani K.A., Jbarah A.A.Q. and Massadeh A. (2004). Inorganic analysis of
dust fall and office dust in an industrial area of Jordan. Environmental
Research 96:139–144.
15. Al-Turki
A.I and Helal M.I.D. (2004). Mobilization of Pb, Zn, Cu and Cd, in Polluted
Soil. Pakistan Journal of Biological
Sciences A. 7:1972-1980.
16. Odabasi
M.M. and Bozlaker A. (2002). Ambient concentration and dry deposition fluxes of
trace elements in Izmir, Turkey. Atmospheric Environment 36:5841-5851.
17. Gemenetzis
P., Moussas P., Arditsoglou A. and Samara C. (2006). Mass concentration and
elemental composition of indoor PM2.5 and PM10 in University rooms in
Thessaloniki, northern Greece. Atmospheric Environment 40: 3195-3206.
18. Gao Y.,
Nelson D.E., Field P.M., Ding Q., Li H., Sherrel M.R., Gigliotti L.C., Van Ry
A.D., Glenn R.T. and Eisenreich J.S. (2002). Characterization of atmospheric
trace elements on PM2.5 particulate matter
over the New York - New Jersey
harbor estuary. Atmospheric Environment 36: 1077-1086.
19. Al-Momani
I.F. (2003). Trace elements in atmospheric precipitation at Northern Jordan
measured by ICP -MS: acidity and possible sources. Atmospheric Environment
37:4507-4515.