Sains Malaysiana 41(4)(2012): 459-463

 

Co-Synthesis and Characterization of In2O3 and ZnO Nanowires

(Sintesis Bersama dan Pencirian bagi Nanowayar In2O3 dan ZnO)

 

Abrar Ismardi1, Chang Fu Dee1*, A. A. Hamzah1, B. Bais2, M. M. Salleh1, B.Y. Majlis1

& Ille C. Gebeshuber1

 

1Institute of Microengineering and Nanoelectronics (IMEN), Universiti Kebangsaan Malaysia

43600, Bangi, Selangor D.E., Malaysia

 

2Departement of Eletrical, Electronics and System Engineering, Universiti Kebangsaan Malaysias

43600, Bangi, Selangor D.E., MalaysiaKebangsaan Malaysias

43600, Bangi, Selangor D.E. Malaysia

 

Diserahkan: 23 Mac 2011 / Diterima: 19 Oktober 2011

 

ABSTRACT

 

Co-synthesis of In2O3 and ZnO nanowires (NWs) were grown on silicon and alumina substrates using vapour transport deposition method. Their morphological structures showed that the NWs were rather aligned on silicon substrate and randomly oriented on alumina substrate. The formation of NWs on silicon substrate was found to be dominated by the growth of ZnO NWs while that on alumina substrate was dominated by the growth of In2O3 NWs. The In2O3 and ZnO NWs were highly crystalline and have wurtzite structure.

 

Keywords: Co-synthesis; In2O3; nanowires; ZnO

 

ABSTRAK

 

Sintesis bersama bagi nanowayar In2O3 dan ZnO telah ditumbuhkan ke atas substrat silikon dan alumina menggunakan kaedah pemendapan wap. Struktur morfologi menunjukkan bahawa nanowayar tumbuh dengan agak teratur di atas substrat silikon manakala secara rawak pada substrat alumina. Penumbuhan nanowayar di atas substrat silicon didominasi oleh nanowayar ZnO, manakala di atas substrat alumina didominasi oleh nanowayar In2O3. Nanowayar In2O3 dan ZnO mempunyai kualiti kristal yang agak tinggi dan berstruktur wursit.

 

Kata kunci: In2O3,; nanowayar; sintesis bersama; ZnO

 

RUJUKAN

 

Bai, S.N., Tsai, H.H. & Tseng, T.Y. 2007. Structural and optical properties of Al-doped ZnO nanowires synthesized by hydrothermal method. Thin Solid Films 516: 155-158.

Cao, B.Q., Lorenz, M., Rahm, A., Wenckstern, H.V., Czekalla, C., Lenzner, J., Benndorf, G. & Grundmann, M. 2007.

Phosphorus acceptor doped ZnO nanowires prepared by pulsed-laser deposition, Nanotechnology 18: 455-707.

Huang, Y., Zhang, Y., Wang, X., Bai, X., Gu, Y., Yan, X., Liao, Q., Qi, J & Liu, J. 2009. Size Independence and Doping Dependence of Bending Modulus in ZnO Nanowires Cryst. Growth Des. 9(4): 1640-1642.

Kar, A., Low, K.B., Oye, M., Stroscio, M.A., Dutta, M., Nicholls, A. & Meyyappan, M. 2011. Investigation of Nucleation Mechanism and Tapering Observed in ZnO Nanowire Growth by Carbothermal Reduction Technique, Nanoscale Res. Lett. 6: 3.

Kim, K., Song, Y.W., Chang, S., Kim, I.H., Kim, S. & Lee, S.Y. 2009. Fabrication and characterization of Ga-doped ZnO nanowire gas sensor for the detection of CO, Thin Solid Films 518: 1190-1193.

Li, L. M., Li, C.C., Zhang, J., Du, Z.F., Zou, B.S., Yu, H.C., Wang, Y.G. & Wang, T.H. 2007. Bandgap narrowing and ethanol sensing properties of In-doped ZnO nanowires. Nanotechnology 18: 225-504.

Li, P.G., Tang, W.H. & Wang, X. 2009. Synthesis of ZnO nanowire arrays and their photoluminescence property. J. Alloys Compound 479 : 634-637

Liu, K.H., Gao, P., Xu, Z., Bai, X.D. & Wang, E.G. 2008. In situ Probing Electrical Response on Bending of ZnO Nanowires Inside Transmission Electron Microscope. Appl. Phys. Lett. 92: 213105.

Mashkoor, A., Jiong, Z., Javed, I., Wei, M, Lin., Rigen, M. & Jing, Z. 2009. Conductivity enhancement by slight indium doping in ZnO nanowires for optoelectronic applications. J. Phys. D: Appl. Phys. 42: 165-406.

Mandalapu, L. J., Xiu, F. X., Yang, Z., Zhao, D.T. & Liu, J.L. 2006. P-type behavior from Sb-doped ZnO heterojunction photodiodes, Appl. Phys. Lett. 88: 112-108.

Marzouki, A., Falyouni, F., Haneche, N., Lusson, A., Galtier, P., Rigutti, L., Jacopin, G., Tchernycheva, M., Oueslati, M. & Sallet. V. 2010. Structural and optical characterizations of nitrogen-doped ZnO nanowires grown by MOCVD. Mater. Lett. 64: 2112–2114.

Pala, E., Hornoka, V., Oszkoc, V. & Dekanya, I. 2009. Hydrothermal synthesis of prism-like and flower-like ZnO and indium-doped ZnO structures. Colloids Surf. A. 340: 1-9.

Park, S. H., Seo, S.Y. & Kim, S.H. 2006. Surface roughness and strain effects on ZnO nanorod growth. Appl. Phys. Lett.88: 251-903.

Yousefi, R., Muhamad, M.R. & Zak, A.K. 2010. Investigation of indium oxide as a self-catalyst in ZnO/ZnInO heterostructure nanowires growth. Thin Solid Films 518 : 5971–5977.

Xu, C.X., Sun, X.W., Zhang, X., Ke, H.L. & Chua, S.J. 2004. Photoluminescent properties of copper-doped zinc oxide nanowires. Nanotechnology 15: 856-861.

Zhou, S.M., Zhang, X.H., Meng, X.M., Fan, X., Wu, S.K. & Lee, S.T. 2005. Preparation and photoluminescence of Sc-doped ZnO nanowires. Physica E 25: 587–591.

 

 

*Pengarang untuk surat-menyurat; email: cfdee@ukm.my

 

 

 

 

sebelumnya