Sains Malaysiana 42(2)(2013): 159–166

 

Rejection of Oil Emulsion using Tubular Surface Filters

(Penyingkiran Emulsi Minyak dengan Penuras Permukaan Tiub)

 

 

Muhammad Abbas Ahmad Zaini*

Centre of Lipids Engineering & Applied Research, Universiti Teknologi Malaysia

81310 Skudai, Johor, Malaysia

 

Iain W. Cumming & Richard G. Holdich

Department of Chemical Engineering, Loughborough University

LE11 3TU, United Kingdom

 

Diserahkan: 3 Jun 2011 / Diterima: 1 September 2012

 

ABSTRACT

This study was aimed to characterize the rejection of oil emulsion by two tubular surface filters, namely 13 μm slots and 4 μm circular pores. A 17 mm helix was incorporated inside the filters to increase the wall shear stress. Rejection of oil, throughputs and flux decay were measured at varying shear stresses (Rw) and transmembrane pressures (TMP). The results showed that the13 μm slots produced a fairly good oil rejection of 22 μm at Rw=0.26 Pa and TMP=6.9 kPa, while the circular pores gave the rejection of 14.4 μm at Rw=0.21 Pa and TMP=34.5 kPa. The results suggested that the circular pores filter could achieve a better oil retention under lower TMP, while the slots filter could be satisfactorily operated under moderate shear stress and low TMP. The increase of TMP offered poor oil rejection by both filters and this was also true for slots-helix configuration.

 

Keywords: Helical insert; microfiltration; oil emulsion; rejection; surface filter

 

ABSTRAK

Kajian ini bertujuan untuk mencirikan penyingkiran emulsi minyak oleh dua penuras permukaan tiub, iaitu 13 μm bukaan celah dan 4 μm bukaan lingkar. Tekanan ricih dinding ditingkatkan dengan menggabungkan 17 mm pilin ke dalam penuras. Penyingkiran minyak, hasil turasan dan kegagalan fluk telah diukur pada tegasan ricih (Rw) dan tekanan transmembran (TMP) yang berbeza. Hasil kajian menunjukkan bahawa 13 μm bukaan celah menghasilkan penyingkiran minyak yang agak baik iaitu 22 μm pada Rw=0.26 Pa dan TMP=6.9 kPa, manakala bukaan lingkar memberikan penyingkiran 14.4 μm pada Rw=0.21 Pa dan TMP=34.5 kPa. Hasil kajian mencadangkan bahawa penuras bukaan lingkar boleh mencapai penahanan minyak lebih baik di bawah TMP yang lebih rendah, manakala penuras bukaan celah boleh dikendalikan dengan sempurna di bawah tegasan ricih sederhana dan TMP yang rendah. Peningkatan TMP memberikan penyingkiran minyak yang rendah bagi kedua-dua penuras dan begitu juga dengan penurasan bukaan celah-pilin.

 

Kata kunci: Emulsi minyak; penurasan mikro; penuras permukaan; penyingkiran; pilin masukan

RUJUKAN

Aul, R.W. & Olbricht, W.L. 1991. Coalescence of freely suspended liquid drops in flow through a small pore. Journal of Colloid and Interface Science 145(2): 478-492.

Chakrabarty, B., Ghoshal, A.K. & Purkait, M.K. 2008. Ultrafiltration of stable oil-in-water emulsion by polysulfone membrane. Journal of Membrane Science 325: 427-437.

Cumming, I.W., Holdich, R.G. & Ismail, B. 1999a. Prediction of deposit depth and transmembrane pressure during crossflow microfiltration. Journal of Membrane Science 154: 229-237.

Cumming, I.W., Holdich, R.G. & Smith, I.D. 1999b. The rejection of oil using an asymmetric metal microfilter to separate an oil in water dispersion. Water Research 33(17): 3587-3594.

Cumming, I.W., Holdich, R.G. & Smith, I.D. 2000. The rejection of oil by microfiltration of a stabilised kerosene/water emulsion. Journal of Membrane Science 169: 147-155.

Desse, M., Mitchell, J., Wolf, B. & Budtova, T. 2011. Droplet deformation and break-up under shear: Hydrocolloid solution vs. suspension of starch granules. Food Hydrocolloids 25: 495-502.

Gordon, G.D. 1959. Mechanism and speed of breakup of drops. Journal of Applied Physics 30(11): 1759-1761.

Hargreaves, J.H. & Silvester, R.S. 1990. Computational fluid dynamics applied to the analysis of deoiling hydrocyclone performance. Trans. IChemE. 68: 365-383.

Holdich, R.G., Cumming, I.W., Kosvintsev, S., Bromley, A.J. & Stefanini, G. 2003. Clarification by slotted surface microfilters. Minerals Engineering 16: 121-128.

International Maritime Organization. 1972. The Paris Convention 1974 and The Oslo Convention 1972. OSPAR 4. Albert Embankment, London.

Koltuniewicz, A.B., Field, R.W. & Arnot, T.C. 1995. Cross-flow and dead-end microfiltration of oily-water emulsion. Part 1: Experimental study and analysis of flux decline. Journal of Membrane Science 102: 193-207.

Kosvintsev, S.R., Sutrisna, P.D., Cumming, I.W., Holdich, R.G. & Mason, G. 2007. The passage of deforming drops through a slotted microfilter. Chemical Engineering Research and Design Trans IChemE, Part A85(A4): 530-536.

Mueller, J., Cen, Y. & Davis, R.H. 1997. Crossflow microfiltration of oily water. Journal of Membrane Science 129: 221-235.

Ohya, H., Kim, J.J., Chinen, A., Aihara, M., Semenova, S.I., Negishi, Y., Mori, O. & Yasuda, M. 1998. Effects of pore size on separation mechanisms of microfiltration of oily water, using porous glass tubular membrane. Journal of Membrane Science 145: 1-14.

Olbricht, W.L. & Kung, D.M. 1987. The interaction and coalescence of liquid drops in flow through a capillary tube. Journal of Colloid and Interface Science 120(1): 229-244.

Ullah, A., Holdich, R.G., Naeem, M. & Starov, V.M. 2012. Stability and deformation of oil droplets during microfiltration on a slotted pore membrane. Journal of Membrane Science 401-402: 118-124.

Varanasi, P.P., Ryan, M.E. & Stroeve, P. 1994. Experimental study on the breakup of model viscoelastic drops in uniform shear flow. Industrial and Engineering Chemistry Research 33: 1858-1866.

Wang, Y., Chen, X., Zhang, J., Yin, J. & Wang, H. 2009. Investigation of microfiltration for treatment of emulsified oily wastewater from the processing of petroleum products. Desalination 249: 1223-1227.

Wolbert, D., Ma, B-F., Aurelle, Y. & Seureau, J. 1995. Efficiency estimation of liquid-liquid hydrocyclones using trajectory analysis. AIChE Journal 41(6): 1395-1401.

Zaini, M.A.A., Holdich, R.G. & Cumming, I.W. 2010. Crossflow microfiltration of oil in water emulsion via tubular filters: evaluation by mathematical models on droplet deformation and filtration. Jurnal Teknologi 53: 19-28.

 

 

*Pengarang untuk surat-menyurat; email: abbas@cheme.utm.my

 

 

 

sebelumnya