Sains Malaysiana 44(3)(2015): 365–370
Isolation
and Characterization of Styryllactone of Goniothalamus ridleyi
(Pemencilan dan Pencirian Stirillakton Goniothalamus ridleyi)
SAMSIAH JUSOH1,4, ZURIATI ZAKARIA2, FASIHUDDIN
B. AHMAD3 & LAILY
B. DIN4*
1Rice
and Industrial Crop Research Centre, Malaysian Agricultural Research and
Development Institute(MARDI), P.O. Box 12301, 50774 Kuala Lumpur, Malaysia
2Malaysia
Japan Institute of Technology, Universiti Teknologi Malaysia, 54100 Kuala
Lumpur
Malaysia
3Department
of Chemistry, Faculty of Resource Science and Technology, Universiti Malaysia
Sarawak, 94300 Kota Samarahan, Sarawak, Malaysia
4School
of Chemical Sciences and Food Technology, Faculty of Science and Technology
Universiti
Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
Diserahkan:
4 Oktober 2013/Diterima: 4 September 2014
ABSTRACT
Phytochemical studies were conducted on the stem bark, stem, root
and fruit of Goniothalamus ridleyi (Annonaceae)
collected at Post Brooke, Gua Musang, Kelantan,
Malaysia. Extraction using organic solvent followed by extensive purification
using standard procedure afforded an epoxystyryllactone,
5-acetoxyisogoniothalamin oxide (1) from the stem bark and fruit; a
styryllactone, 5-acetoxygoniothalamin (2) and a styrylpyrone,
dehydrogoniothalamin (3) from the stem and root; a styryllactone,
5-hydroxygoniothalamin (4) from the root and styrylpyrone as well as
goniothalamin (5) from the fruit. These compounds were characterized using
spectroscopic techniques.
Keywords: Annonaceae; goniothalamin derivatives; Goniothalamus; NMR
ABSTRAK
Kajian fitokimia telah dijalankan ke atas kulit
batang, batang, akar dan buah Goniothalamus ridleyi (Annonaceae) yang diperoleh dari Post
Brooke, Gua Musang, Kelantan, Malaysia. Pengekstrakan menggunakan pelarut organik
diikuti dengan pemisahan ekstensif menggunakan prosedur piawai menghasilkan
epoksistirillakton, 5-asetoksiisogoniotalamin oksida (1) daripada kulit batang
dan buah; stirillakton, 5-asetoksigoniotalamin (2) dan stirilpiron,
dehidrogoniotalamin (3) daripada batang dan akar; stirillakton,
5-hidroksigoniotalamin (4) daripada akar dan stirilpiron manakala goniotalamin
(5) daripada buah. Sebatian-sebatian ini dikenal pasti
menggunakan teknik spektroskopi.
Kata kunci: Annonaceae; Goniothalamus; NMR; terbitan
goniothalamin
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*Pengarang
untuk surat-menyurat; email: lbdin@ukm.edu.my
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