Sains Malaysiana 51(1)(2022): 161-173

http://doi.org/10.17576/jsm-2022-5101-13

Adsorptive Performance of Congo Red using Copper-Aluminum LDHS Load to Rice Husk Biochar

(Prestasi Penjerapan Kongo Merah menggunakan Beban Tembaga-Aluminium LDHS kepada Bioarang daripada Sekam Padi)

NEZA RAHAYU PALAPA¹, NOVIE JULEANTI², NORMAH², TARMIZI TAHER³, RISFIDIAN MOHADI⁴, ADDY RACHMAT⁴ & ALDES LESBANI^1,2*

¹Graduate School, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang-Prabumulih, Km. 32, Ogan Ilir, South Sumatera, Indonesia

²Research Center of Inorganic Materials and Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Padang Selasa Bukit Besar Palembang, 30139 South Sumatera, Indonesia

³Department of Environmental Engineering, Institut Teknologi Sumatera, Jalan Terusan Ryacudu, Way Hui, Kecamatan Jati Agung, Lampung Selatan 35365, Indonesia

⁴Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang-Prabumulih, Km. 32, Ogan Ilir, South Sumatera, Indonesia

Diserahkan: 7 Februari 2021/Diterima: 22 April 2021

ABSTRACT

This work aimed that CuAl layered double hydroxide (LDH) is loaded to biochar to form CuAlLDH@BC composites by co-precipitation methods. CuAlLDH@BC composite was prepared and characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, surface area specific analysis BET method, thermalgravimetric, and scanning electron microscopy (SEM) for morphological analysis. CuAlLDH@BC composite used as adsorbent for the removal of Congo red. The adsorption ability of CuAlLDH@BC composite evaluated by pseudo-second-order kinetic model, with Qe_calculated and Qe_experimental of the composite were closed (47.619 and 46.143 mg/g, respectively). Furthermore, the adsorption conducts were more consistent with the Langmuir isotherm model, than the Freundlich isotherm model. The isotherm adsorption data obtained the maximum adsorption capacity was 61.350 mg/g. Thermodynamic studies illustrated the endothermic nature of CuAlLDH@BC, as well as the fact that the adsorption process is spontaneous. Thus, CuAlLDH@BC showed a high reusability performance even after third cycle of adsorption-desorption process.

Keywords: Adsorption; biochar; composite; congo red; layered double hydroxide

ABSTRAK

Kajian ini bertujuan supaya hidroksida berganda berlapis CuAl (LDH) dimuatkan ke bioarang untuk membentuk komposit CuAlLDH@BC melalui kaedah kerpasan bersama. Komposit CuAlLDH@BC telah disedia dan dicirikan oleh pembelauan sinar-X (XRD), spektroskopi inframerah transformasi Fourier (FTIR), kaedah BET analisis khusus luas permukaan, gravimetrik terma dan mikroskop elektron pengimbasan (SEM) untuk analisis morfologi. Komposit CuAlLDH@BC digunakan sebagai penjerap untuk penyingkiran merah Kongo. Keupayaan penjerapan komposit CuAlLDH@BC dinilai oleh model kinetik kedua pseudo dengan Qe_calculated dan Qe_experimental komposit telah ditutup (masing-masing 47.619 dan 46.143 mg/g). Tambahan pula, kelakuan penjerapan lebih tekal dengan model isoterma Langmuir, berbanding model isoterma Freundlich. Data penjerapan isoterma memperoleh kapasiti penjerapan maksimum ialah 61.350 mg/g. Kajian termodinamik menggambarkan sifat endotermik CuAlLDH@BC serta hakikat bahawa proses penjerapan adalah spontan. Oleh itu, CuAlLDH@BC menunjukkan prestasi kebolehgunaan semula yang tinggi walaupun selepas kitaran ketiga proses penjerapan-desorpsi.

Kata kunci: Bioarang; hidroksida berganda berlapis; komposit; Kongo merah; penjerapan

RUJUKAN

Abdelrahman, E.A. 2018. Synthesis of zeolite nanostructures from waste aluminum cans for efficient removal of malachite green dye from aqueous media. Journal of Molecular Liquids 253(2017): 72-82.

Ahmed, D.N., Naji, L.A., Faisal, A.A.H., Al-Ansari, N. & Naushad, M. 2020. Waste foundry sand/MgFe-layered double hydroxides composite material for efficient removal of Congo red dye from aqueous solution. Scientific Reports 10(1): 1-12.

Azargohar, R. & Dalai, A.K. 2006. Biochar as a precursor of activated carbon. Applied Biochemistry and Biotechnology. In Twenty-Seventh Symposium on Biotechnology for Fuels and Chemicals 131(1-3): 762-773.

Boutemak, K., Taoualit, N., Cheknane, B., Laslouni, O., Djeddou, S., Medaoud, K., Mazouni, I. & Aoudj, S. 2019. Equilibirium, kinetic and thermodynamic study of green malachite and rhodamine-B dyes sorption on olive pomace. Chemical Engineering Transactions 73: 277-282.

Bukhtiyarova, M.V. 2019. A review on effect of synthesis conditions on the formation of layered double hydroxides. Journal of Solid State Chemistry 269: 494-506.

Callister, J.W.D. 2000. Materials Science and Engineering: An Introduction. 5th ed. New York: John Wiley & Sons.

Chakraborty, P. & Nagarajan, R. 2015. Efficient adsorption of malachite green and Congo red dyes by the surfactant (DS) intercalated layered hydroxide containing Zn²⁺ and Y³⁺-ions. Applied Clay Science 118: 308-315.

Cui, J., Zhang, F., Li, H., Cui, J., Ren, Y. & Yu, X. 2020. Recent progress in biochar-based photocatalysts for wastewater treatment: Synthesis, mechanisms, and applications. Applied Sciences 10(3): 1019.

Firdaus, M.L., Krisnanto, N., Alwi, W., Muhammad, R. & Serunting, M.A. 2017. Adsorption of textile dye by activated carbon made from rice straw and oil palm midrib. Aceh International Journal of Science and Technology 6(1): 1.

Foroutan, R., Mohammadi, R., Razeghi, J. & Ramavandi, B. 2019. Performance of algal activated carbon/Fe₃O₄ magnetic composite for cationic dyes removal from aqueous solutions. Algal Research 40: 101509.

Gholami, P., Khataee, A., Soltani, R.D.C., Dinpazhoh, L. & Bhatnagar, A. 2020. Photocatalytic degradation of gemifloxacin antibiotic using Zn-Co-LDH@biochar nanocomposite. Journal of Hazardous Materials 382: 121070.

Hu, H., Liu, J., Xu, Z., Zhang, L., Cheng, B. & Ho, W. 2019. Hierarchical porous Ni/Co-LDH hollow dodecahedron with excellent adsorption property for Congo red and Cr(VI) ions. Applied Surface Science 478: 981-990.

Huang, D., Liu, C., Zhang, C., Deng, R., Wang, R., Xue, W., Luo, H., Zheng, G., Zhang, Q. & Guo, X. 2019. Cr(VI) removal from aqueous solution using biochar modified with Mg/Al-layered double hydroxide intercalated with ethylenediaminetetraacetic acid. Bioresource Technology 276: 127-132.

Inumaru, K., Ishihara, T., Kamiya, Y., Okuhara, T. & Yamanaka, S. 2007. Water-tolerant, highly active solid acid catalysts composed of the keggin-type polyoxometalate H3PW12O40 immobilized in hydrophobic nanospaces of organomodified mesoporous silica. Angewandte Chemie - International Edition 46(40): 7625-7628.

Lafi, R., Charradi, K., Djebbi, M.A., Ben Haj Amara, A. & Hafiane, A. 2016. Adsorption study of Congo red dye from aqueous solution to Mg-Al-layered double hydroxide. Advanced Powder Technology 27(1): 232-237.

Lesbani, A., Taher, T., Palapa, N.R., Mohadi, R., Rachmat, A. & Mardiyanto. 2020. Preparation and utilization of Keggin-type polyoxometalate intercalated Ni-Fe layered double hydroxides for enhanced adsorptive removal of cationic dye. SN Applied Sciences 2: 470.

Lian, L., Guo, L. & Guo, C. 2009. Adsorption of Congo red from aqueous solutions onto Ca-bentonite. Journal of Hazardous Materials 161(1): 126-131.

Lorenc-Grabowska, E. & Gryglewicz, G. 2007. Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon. Dyes and Pigments 74(1): 34-40.

Ma, J., Ding, J., Yu, L., Li, L., Kong, Y. & Komarneni, S. 2015. BiOCl dispersed on NiFe-LDH leads to enhanced photo-degradation of Rhodamine B dye. Applied Clay Science 109-110: 76-82.

Mahjoubi, F.Z., Elhalil, A., Elmoubarki, R., Sadiq, M., Khalidi, A., Cherkaoui, O. & Barka, N. 2017. Performance of Zn ‐ , Mg ‐ and Ni ‐ Al layered double hydroxides in treating an industrial textile wastewater. Journal of Applied Sciences and Interfaces 2(1-3): 1-11.

Malak-Polaczyk, A., Vix-Guterl, C. & Frackowiak, E. 2010. Carbon/layered double hydroxide (LDH) composites for supercapacitor application. Energy and Fuels 24(6): 3346-3351.

Mao, N. & Jiao, Y. 2018. CuAl hydrotalcite formed CuAl-Mixed metal oxides for photocatalytic removal of rhodamine B and Cr(VI). ChemistrySelect 3(44): 12676-12681.

Meili, L., Lins, P.V., Zanta, C.L.P.S., Soletti, J.I., Ribeiro, L.M.O., Dornelas, C.B., Silva, T.L. & Vieira, M.G.A. 2019. MgAl-LDH/Biochar composites for methylene blue removal by adsorption. Applied Clay Science 168: 11-20.

Mittal, A., Mittal, J., Malviya, A. & Gupta, V.K. 2009. Adsorptive removal of hazardous anionic dye ‘‘Congo red” from wastewater using waste materials and recovery by desorption. Journal of Colloid And Interface Science 340(1): 16-26.

Mohammed, M.I. & Baytak, S. 2016. Synthesis of bentonite-carbon nanotube nanocomposite and its adsorption of rhodamine dye from water. Arabian Journal for Science and Engineering 41(12): 4775-4785.

Namasivayam, C. & Kavitha, D. 2002. Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes and Pigments 54(1): 47-58.

Nisar, J., Sayed, M., Ullah, F., Mahmood, H., Iqbal, M., Ali, R. & Anas, M. 2016. Gamma - irradiation induced degradation of diclofenac in aqueous solution: Kinetics, role of reactive species and influence of natural water parameters. Biochemical Pharmacology 4(2): 2573-2584.

Palapa, N.R., Juleanti, N., Normah, N., Taher, T. & Lesbani, A. 2020a. Unique adsorption properties of malachite green on interlayer space of Cu-Al and Cu-Al-SiW12O40 layered double hydroxides. Bulletin of Chemical Reaction Engineering & Catalysis 15(3): 653-661.

Palapa, N.R., Mohadi, R., Rachmat, A. & Lesbani, A. 2020b. Adsorption study of malachite green removal from aqueous solution using Cu/M³⁺ (M³⁺ = Al, Cr) layered double hydroxide. Mediterranean Journal of Chemistry 10(1): 33-45.

Parida, K.M. & Mohapatra, L. 2012. Carbonate intercalated Zn/Fe layered double hydroxide: a novel photocatalyst for the enhanced photo degradation of azo dyes. Chemical Engineering Journal 179: 131-139.

Patterson, R.F. & Savas, E. 2016. On P-convergence of four dimensional weighted sums of double random variables. Sains Malaysiana 45(7): 1177-1181.

Peng, C., Dai, J., Yu, J. & Yin, J. 2015. Calcined Mg-Fe layered double hydroxide as an absorber for the removal of methyl orange. AIP Advances 5(5): 057138.

Raval, N.P., Shah, P.U. & Shah, N.K. 2016. Adsorptive amputation of hazardous azo dye Congo red from wastewater: A critical review. Environmental Science and Pollution Research 23(15): 14810-14853.

Schwarzenbach, R.P., Egli, T., Hofstetter, T.B., von Gunten, U. & Wehrli, B. 2010. Global water pollution and human health. Annual Review of Environment and Resources 35(1): 109-136.

Shenvi, S.S., Isloor, A.M., Ismail, A.F., Shilton, S.J. & Al Ahmed, A. 2015. Humic acid based biopolymeric membrane for effective removal of methylene blue and rhodamine b. Industrial and Engineering Chemistry Research 54(18): 4965-4975.

Soleimani, K., Tehrani, A.D.D. & Adeli, M. 2018. Bioconjugated graphene oxide hydrogel as an effective adsorbent for cationic dyes removal. Ecotoxicology and Environmental Safety 147: 34-42.

Sriram, G., Uthappa, U.T., Kigga, M., Jung, H.Y., Altalhi, T., Brahmkhatri, V. & Kurkuri, M.D. 2019. Xerogel activated diatoms as an effective hybrid adsorbent for the efficient removal of malachite green. New Journal of Chemistry 43(9): 3810-3820.

Thommes, M., Kaneko, K., Neimark, A.V., Olivier, J.P., Rodriguez-Reinoso, F., Rouquerol, J. & Sing, K.S.W. 2015. Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution. Pure and Applied Chemistry 87(9-10): 1051-1069.

Tran, H.N., Lin, C.C., Woo, S.H. & Chao, H.P. 2018. Efficient removal of copper and lead by Mg/Al layered double hydroxides intercalated with organic acid anions: Adsorption kinetics, isotherms, and thermodynamics. Applied Clay Science 154: 17-27.

Vikrant, K., Giri, B.S., Raza, N., Roy, K., Kim, K.H., Rai, B.N. & Singh, R.S. 2018. Recent advancements in bioremediation of dye: Current status and challenges. Bioresource Technology 253: 355-367.

Wang, S., Gao, B., Li, Y., Zimmerman, A.R. & Cao, X. 2016. Sorption of arsenic onto Ni/Fe layered double hydroxide (LDH)-biochar composites. RSC Advances 6(22): 17792-17799.

Wu, X.L., Wang, L., Chen, C.L., Xu, A.W. & Wang, X.K. 2011. Water-dispersible magnetite-graphene-LDH composites for efficient arsenate removal. Journal of Materials Chemistry 21(43): 17353-17359.

Xia, Y., Yang, T., Zhu, N., Li, D., Chen, Z., Lang, Q., Liu, Z. & Jiao, W. 2019. Enhanced adsorption of Pb(II) onto modified hydrochar: Modeling and mechanism analysis. Bioresource Technology 288: 1-8.

Zainol, M.M., Amin, N.A.S. & Asmadi, M. 2017. Preparation and characterization of impregnated magnetic particles on oil palm frond activated carbon for metal ions removal. Sains Malaysiana 46(5): 773-782.

Zhang, M. & Gao, B. 2013. Removal of arsenic, methylene blue, and phosphate by biochar/AlOOH nanocomposite. Chemical Engineering Journal 226: 286-292.

Zhu, Z., Ouyang, S., Li, P., Shan, L., Ma, R. & Zhang, P. 2020. Persistent organic pollutants removal via hierarchical flower-like layered double hydroxide: Adsorption behaviors and mechanism investigation. Applied Clay Science 188: 105500.

Zubair, M., Manzar, M.S., Mu’azu, N.D., Anil, I., Blaisi, N.I. & Al-Harthi, M.A. 2020. Functionalized MgAl-layered hydroxide intercalated date-palm biochar for enhanced uptake of cationic dye: Kinetics, isotherm and thermodynamic studies. Applied Clay Science 190: 105587.

*Pengarang untuk surat-menyurat; email: aldeslesbani@pps.unsri.ac.id