Sains Malaysiana 52(5)(2023): 1419-1434

http://doi.org/10.17576/jsm-2023-5205-08

Effect of Arginine-Based Deep Eutectic Solvents on Supported Porous Sorbent for CO₂ Capture Analysis

(Kesan Pelarut Eutektik Dalam Berasaskan Arginina pada Bahan Penjerap Poros Berpenyokong untuk Analisis Penangkapan CO₂)

NABILAH SUHAILI^1,2,LEE WAH LIM², LEE PENG TEH¹, SITI NURZUBAIDA SHAHDAN¹, ZAITUN GHAZALI³ MANABU MIYAMOTO², SHIGEYUKI UEMIYA² & RIZAFIZAH OTHAMAN^1,4,*

¹Department of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

²Graduated School of Engineering, Faculty Engineering, Gifu University, 1-1 Yanagido, Gifu-Shi, 501-1193, Japan

³Institute of Teacher Education, Technical Education Campus, Bandar Enstek, 71760 Nilai, Negeri Sembilan Darul Khusus, Malaysia

⁴Polymer Research Center (PORCE), Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

Diserahkan: 28 Februari 2023/Diterima: 8 Mei 2023

Abstract

Carbon dioxide (CO₂) as one of the heat-trapping gases, has caused global warming. Being a greener and more economical material, amino acid-based deep eutectic solvents (AADES) have attracted interest in CO₂ capture applications. In this paper, the effect of L-arginine (Arg) in binary AADES of arginine-ethylene glycol (Arg-EG) and ternary AADES of choline chloride-ethylene glycol-arginine (ChCl-EG-Arg) on adsorption of CO₂ was studied. The solubility, basicity, and physicochemical characteristics were compared with the binary DES (ChCl-EG) before and after being impregnated into a silica gel (SG) via the wet impregnation method. The AADES/SG adsorbents were evaluated for CO₂ sorption performance using an automated gas sorption analyzer at 100% CO₂ loading and thermogravimetric analysis (TGA) at flue gas conditions (15% CO₂/85% N₂). Findings show the basicity and the nitrogen content (N%) of AADES/SG were increased as Arg was added and DES/AADES functional group peaks (amino, hydroxyl, alkyl groups) were observed after the impregnation. The CO₂ sorption of 16.0 mg/g at 25 °C and 1 atm was achieved by 30% Arg-EG(1:8)/SG followed by 30% ChCl-EG-Arg (1:2:0.1)/SG (14.8 mg/g) and 30% ChCl-EG/SG(1:2) (14.5 mg/g) using an Autosorb iQ₂ instruments with 100% CO₂ loading. The CO₂ uptake was increased almost linearly with increasing pressure and decreased with increasing temperature. The  Arg-EG(1:8)/SG shows the highest selectivity toward CO₂ than other sorbents with 8.10 mg/g adsorption for 1 h at 15% CO₂ loading at 25 °C with higher thermal stability and surface area. Considering environmental, technological, and economic viewpoints, the Arg-EG(1:8)/SG can be explored more as a potential solid sorbent for CO₂ capture.

Keywords: Amino acid; carbon dioxide adsorption; deep eutectic solvent; silica sorbent; wet-impregnation

Abstrak

Karbon dioksida (CO₂) sebagai salah satu gas perangkap haba telah menyebabkan pemanasan global. Sebagai bahan yang lebih hijau dan lebih menjimatkan, pelarut eutektik dalam berasaskan asid amino (AADES) telah menarik minat dalam aplikasi penangkapan CO₂. Dalam kajian ini, kesan L-arginina (Arg) dalam AADES binari bagi arginina-etilena glikol (Arg-EG) dan ternari AADES bagi klorida kolina-etilena glikol arginina (ChCl-EG-Arg) terhadap penjerapan CO₂ telah dikaji. Kelarutan, kebesan dan ciri-ciri fizikokimia sebelum dan selepas diisi ke dalam gel silika (SG) melalui kaedah pengisitepuan basah telah dibandingkan dengan binari DES (ChCl-EG). Penjerap AADES/SG telah dinilai untuk prestasi penjerapan CO₂ menggunakan analisis penjerapan gas automatik pada 100% muatan CO₂ dan analisis termogravimetri (TGA) pada keadaan gas serombong (15% CO₂/85% N₂). Penemuan menunjukkan bahawa kebesan dan kandungan nitrogen (N%) AADES telah meningkat apabila Arg ditambah dan puncak kumpulan berfungsi AADES (kumpulan amino, hidroksi dan alkil) telah diperhatikan selepas pengisitepuan. Penjerapan CO₂ sebanyak 16.0 mg/g pada 25 °C dan 1 atm telah dicapai oleh 30% Arg-EG(1:8)/SG diikuti oleh 30% ChCl-EG/SG(1:2) (14.5 mg/g) menggunakan instrument Autosorb iQ₂ dengan 100% muatan CO₂. Penjerapan CO₂ meningkat secara linear dengan peningkatan tekanan dan berkurang dengan peningkatan suhu. Arg-EG(1:8)/SG menunjukkan kepilihan tertinggi terhadap CO₂ berbanding dengan penjerap lain dengan penjerapan sebanyak 8.10 mg/g selama 1 jam pada 15% muatan CO₂ pada 25 °C dengan kestabilan termal dan kawasan permukaan yang lebih tinggi. Mengambil kira sudut alam sekitar, teknologi dan ekonomi, Arg-EG(1:8)/SG boleh diteroka lebih lanjut sebagai penjerap pepejal yang berpotensi untuk penangkapan CO₂.

Kata kunci: Asid amino; pelarut eutektik dalam; pengisitepuan basah; penjerapan karbon dioksida; penjerap silika

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