Malaysian
Journal of Analytical Sciences Vol 20 No 2 (2016): 444 - 451
THE POTENTIAL OF COCONUT SHELL POWDER (CSP) AND
COCONUT SHELL ACTIVATED CARBON (CSAC) COMPOSITES AS ELECTROMAGNETIC
INTERFERENCE (EMI) ABSORBING MATERIAL
(Potensi Serbuk Tempurung Kelapa (CSP) dan Karbon
Teraktif Tempurung Kelapa (CSAC) Sebagai Bahan Penyerap Gangguan
Elektromagnatik)
Siti Nurbazilah Ab. Jabal1, Yew Been Seok1*, Wee
Fwen Hoon2
1Faculty of Innovative Design and Technology,
Universiti
Sultan Zainal Abidin, Kampus Gong Badak, 21300 Kuala Terengganu, Terengganu,
Malaysia
2Embedded Computing Research Cluster, School of
Computer and Communication Engineering,
Universiti Malaysia Perlis, Jalan Kangar-Alor Star, Taman
Pertiwi Indah Seriab, 01000 Kangar, Perlis, Malaysia
*Corresponding author: bseokyew@unisza.edu.my
Received: 14
April 2015; Accepted: 30 November 2015
Abstract
Agriculture waste is potentially useful as an alternative material to
absorb and attenuates electromagnetic interference (EMI). This research
highlights the use of coconut shell powder (CSP) and coconut shell activated
carbon (CSAC) as raw materials with epoxy resin and amine hardener composite to
absorb microwave signals over frequency of 1 – 8 GHz. In order to investigate
the suitability of these raw materials as EMI absorbing material, carbon
composition of the raw materials is determined through CHNS Elemental Analysis.
The surface morphology of the raw materials in term of porosity is investigated
by using TM3000 Scanning Electron Microscope (SEM). The complex permittivity of
the composites is determined by using high temperature dielectric probe in conjunction
with Network Analyzer. From the result, the Carbon% of CSP and CSAC is 46.70%
and 84.28% respectively. In term of surface morphology, the surface porosity of
CSP and CSAC is in the range of 2 µm and 1µm respectively. For the dielectric
properties, the dielectric constant and the dielectric loss factor for CSP and
CSAC is 4.5767 and 64.8307and 1.2144 and 13.8296 respectively. The materials
more potentially useful as substitute materials for electromagnetic
interference (EMI) absorbing are discussed.
Keywords: agricultural
wastes, dielectric properties, carbon composition
Abstrak
Sisa pertanian mempunyai potensi untuk digunakan sebagai bahan
alternatif untuk menyerap atau melemahkan gangguan elektromagnatik (EMI). Kajian
ini menekankan kepada penggunaan serbuk tempurung kelapa (CSP) dan karbon
teraktif tempurung kelapa(CSAC) sebagai bahan mentah dengan campuran resin
epoksi dan komposit penguat amina untuk menyerap gelombang mikro dalam frekuensi
1 – 8 GHz. Bagi mengkaji kesesuaian bahan
mentah sebagai bahan penyerap gelombang mikro, komposisi karbon dalam bahan mentah
ditentukan mengunakan analisis unser CHNS. Liang permukaan bahan mentah pula
dikaji mengunakan mikroskop pengimbas elektron TM3000 (SEM). Ketelusan kompleks bagi bahan campuran diukur menggunakan prob
dielektrik suhu tinggi dan alat analisis rangkaian. Daripada keputusan yang diperolehi,
peratusan karbon dalam CSP dan CSAC adalah sebanyak 46.70 % dan 84.28 %. Manakala
dari segi liang permukaan pula, keliangan CSP dan CSAC masing – masing berada dalam
lingkungan 2um dan 1um.Bagi sifat dielektrik, pemalar dielektrik untuk CSP dan
CSAC masing – masing adalah 4.5767 dan 64.8307. Bagi pembelauan dielektrik,
nilai untuk CSP dan CSAC masing – masing adalah 1.2144 dan 13.8296. Isu bahan
yang lebih berpotensi untuk digunakan sebagai
bahan penyerap gangguan elektromagnatik (EMI) dibincangkan.
Kata kunci: sisa pertanian, sifat dielektrik, komposisi karbon
References
1.
Salleh M. K. M.,
Yahya M., Awang Z., Muhamad W. N. W., Mozi A.M. and Yaacob N. (2011). Single layer
coconut shell – based microwave absorber.
IEEE TENCON: pp 1110 – 1113.
2.
Sivakumar, K.
and Mohan, N. K. (2010). Performance analysis of downdraft gasifier for
agriwaste biomass materials. Indian
Journal of Science and Technology, 3: 58 – 60.
3.
Daud, W. M. A.
W. and Ali, W. S. W. (2004). Comparison on pore development of activated carbon
produced from palm shell and coconut shell. Bioresource
Technology, 93: 63 – 69.
4.
Cobb, A., Warms,
M., Maurer, E. P. and Chiesa, S. (2012).
Low-tech coconut shell activated charcoal production. International Journal for Service Learning in Engineering, 7: 93
–104.
5.
Chandra, T. C.,
Mirna, M. M., Sunarso, J., Sudaryanto, Y. and Ismadji, S. (2009). Activated carbon
from durian shell: preparation and characterization. Journal of Taiwan Institute Chemical Engineering. 40: 457 – 462.
6.
Tay, T., Ucar, S.
and Karagoz, S. (2009). Preparation and characterization of activated carbon
from waste biomass. Journal of Hazardous
Materials, 165: 481 – 485.
7.
Cresswell, G.,
(2011). Coir dust a proven alternative to peat. Cresswell Horticulrutal Services (Report): 1 – 13.
8.
Yusof, A. A. (2004).
Thesis The development of microwave absorber from oil palm shell carbon.
9.
Yusof, A. A., Ali,
W. K. W., Rahman, T. A. and Ani F. N. (2005). Microwave and reflection
properties of palm shell carbon-polyester conductive composite absorber. Jurnal Teknologi, 42: 59 – 74.
10.
Zahid, L., Malek,
M. F. B. A., Nornikman, H., Mohd Affendi, N. A., Ali, A., Hussin, N., Ahmad B.
H. and Abdul Aziz, M. Z. A. (2013). Development of pyramidal microwave absorber
using sugar cane bagasse (SCB). Progress
in Electromagnetics Research, 137: 687 – 702.
11.
Menéndez, J. A.,
Arenillas, A., Fidalgo, B., Fernández, Y., Zubizarreta, L., Calvo, E. G. and Bermúdez,
J. M. (2010). Microwave heating processes involving carbon materials. Fuel Processing Technology, 91: 1 – 8.
12.
Information from
Biofuels Research Infrastructure for Sharing Knowledge (BRISK), Database for
biomass and waste, Retrived from https://www.ecn.nl/phyllis2/
13.
Achaw, O-W. and Afrane,
G. (2008). The evolution of pore structure of coconut shells during the
preparation of cocnut shell-based activated carbons. Microporous and Mesoporous Materials, 112: 284 – 290.
14.
Mfanacho, S. M.,
Hemang, P. and Manocha, L. M. (2010). Enhancement of microporosity through physical
activation. PRAJÑĀ - Journal of Pure and Applied Sciences,
18: 106 – 109.
15.
Saini, P., Arora,
M. and Ailton, D.S.G. (2012). Microwave absorption and EMI shielding behaviour
of nanocomposites based on intrinsically conducting polymers, graphene and
carbon nanotubes. In Chapter 3. Crotia: InTech Publishing: pp 1 – 42.
16.
Li, S., Chen, S.,
Anwar, S., Lu, W., Lai, Y., Chen, H., Hou, B., Ren, B, F. and Gu, B. (2012).
Applying Effective Medium Theory in Characterizing Dielectric Constant of
Solids. Progress in Electromagnetics
Research. 35: 145 –153.
17.
Micheli, D., Apollo,
C., Pastore, R., Morles, R.B., Marchetti, M., Gradoni, G. edited by Reddy, B.
(2011). Electromagnetic characterization of composite materials and microwave
absorbing modelling in Chapter 16. InTech Publishing: pp 359 – 384.
18.
Thompson, M.
(2008). CHNS Elemental Analysers (Analytical Methods Committee). Royal Chemical
Society: pp 1 – 2.
19.
Meena, P. L., Saxena,
R. and Sharma, N. (2014). A rapid analytical method using flow injection preconcentration
of zinc on dithizone impregnated on amberlite XAD-2 and its determination in
water samples by FAAS. International
Journal of Agriculture and Food Science Technology, 5: 287 – 296.
20.
Koboski, K. R., Nelsen,
E. F. and Hampton, J. R. (2013). Hydrogen evolution reaction measurements of dealloyed
porous NiCu. Nanoscale Research Letters,
8: 528 – 535.
21.
Hoon, W. F., Jack,
S. P., Malek, M. F. A. and Hasssan, N. (2012). Alternatives for pcb laminates:
dielectric properties' measurements at microwave frequencies in Chapeter 5. InTech
Publishing.
22.
Chakma, S., Vaishya,
R. C. and Yadav, A. K. (2015). Modeling chemical compositions of municipal
solid waste. Environmental Geotechnics
(Article in Press): September 11, 2015
23.
Cazetta, A. L., Vargas,
A. M. M., Nogami, E. M., Kunita, M. H., Guiherme, M. R., Martins, A. C., Silva,
T. L., Moraes, J. C. G. and Almeid, V. C. (2011). NaOH activated carbon of high
surface area produced from coconut shell: kinetics and equilibrium studies from
the methylene blue adsorption. Chemical
Engineering Journal, 174: 117 – 125.
24.
Demiral, H.,
Demiral, I., Karabacakoglu, B. and Tumsek. F. (2011). Production of activated
carbon from olive bagasse by physical activation. Chemical Engineering Research and Design, 89: 206 – 213.
25.
Nasria, N. S., Jibrila,
M., Zaini, M .A. A., Mohsin, R. Daduma, H. U. and Musa, A. M. (2014). Synthesis
and characterization of green porous carbons with large surface area by two
step chemical activation with KOH. Jurnal
Teknologi. 67(4): 25 – 28.
26.
Bhatnagar, A.,
Hogland, W., Marques, M. and Sillanpaa, M. (2013). An overview of the
modification methods of activated carbon for its water treatment applications. Chemical Engineering Journal, 219: 499 –
511.
27.
Iqbaldin, M. M.,
Khudzir, I., Azlan, M. M., Zaidi, A. G., Surani, B. and Zubri, Z. (2013).
Properties of coconut shell activated carbon. Journal of Tropical Forest Science, 25: 497 – 503.
28.
Atwater, J. E.
and Jr. R.R. Wheeler. (2004). Microwave permittivity and dielectric relaxation
of a high surface area activated carbon.
IEEE Electrical Insulation Magazine, 17(2): 66 – 66.