Sains Malaysiana 48(1)(2019): 155–164
http://dx.doi.org/10.17576/jsm-2019-4801-18
A Review
of Wastewater Treatment using Natural Material and Its Potential as Aid and
Composite Coagulant
(Suatu Penilaian
Perawatan Sisa Air menggunakan Bahan Semula Jadi dan Potensinya
sebagai Pembantu dan Komposit Koagulan)
SITI NOR AISHAH MOHD-SALLEH*, NUR SHAYLINDA MOHD-ZIN
& NORZILA OTHMAN
Department
of Water and Environmental Engineering, Faculty of Civil and Environmental
Engineering, Universiti Tun Hussien Onn Malaysia, 86400 Parit Raja, Johor Darul
Takzim, Malaysia
Diserahkan:
3 April 2018/Diterima: 13 September 2018
ABSTRACT
The introduction of natural materials into the
coagulation-flocculation process need to be practiced as common as possible.
The previous literature indicated that utilization of natural material is
actually worth to be developed and if possible, into the commercial one.
However, the application of natural coagulants itself as the primary treatment
is not sufficient, due to the rise in constraints which limited its
performance. Emerging technologies and depth studies are actually helping these
limited conditions to grow them as good as the performance of chemical
coagulants. Alternatively, the natural-based coagulants are commonly used as
coagulant aids alongside chemical coagulants, which have created a highlight in
water research. This review covers the type of coagulants used in the
coagulation-flocculation of wastewater treatment especially in the usage of
natural-based coagulants. This review paper also outlines the future prospects
of natural materials as aids and its potential as sustainable composite
coagulants.
Keywords: Chemical coagulant; composite coagulant; natural
material; wastewater
ABSTRAK
Pengenalan bahan-bahan semula jadi ke dalam proses
pemberbukuan-pembekuan perlu diamalkan sedapat mungkin. Kepustakaan terdahulu
menunjukkan bahawa penggunaan bahan semula jadi sebenarnya berbaloi untuk
dibangunkan dan jika boleh secara komersial. Walau bagaimanapun, penggunaan koagulan
semula jadi sendiri sebagai rawatan utama tidak mencukupi, disebabkan oleh
peningkatan kekangan yang membatasi prestasinya. Teknologi yang berkembang dan
kajian mendalam sebenarnya membantu keadaan terhad ini untuk membangunkannya
menjadi sebaik prestasi koagulan kimia. Sebagai alternatif, koagulan berasaskan
semula jadi biasanya digunakan sebagai alat koagulan di samping koagulan kimia,
yang telah menarik perhatian dalam penyelidikan air. Kajian ini merangkumi
jenis-jenis koagulan yang digunakan dalam pemberbukuan-pembekuan pembuangan air
sisa terutamanya dalam penggunaan koagulan berasaskan semula jadi. Kertas ini
juga menggariskan prospek masa depan bahan semula jadi sebagai bantuan dan
potensinya sebagai koagulan komposit yang mampan.
Kata kunci:
Air sisa; bahan semula jadi; koagulan kimia; komposit koagulan
RUJUKAN
Abidin, Z.Z., Ismail, N., Yunus, R., Ahamad, I.S. &
Idris, A. 2011. A preliminary study on Jatropha curcas as coagulant in
wastewater treatment. Environmental Technology 32(9): 71-77.
Al-Sameraiy, M. 2012. A novel water pretreatment approach
for turbidity removal using date seeds and pollen sheath. Journal of Water
Resource and Protection 4(2): 79-92.
Altaher, H., Tarek, E.K. & Abubeah, R. 2016. An
agricultural waste as a novel coagulant aid to treat high turbid water
containing humic acids. Global Nest Journal 18(2): 279-290.
Amagloh, F.K. & Benang, A. 2009. Effectiveness of Moringa
oleifera seed as coagulant for water purification. African Journal of
Agricultural Research 4(2): 119-123.
Awang, N.A. & Aziz, H.A. 2012. Hibiscus rosa-sinensis leaf extract as coagulant aid in leachate treatment. Applied Water
Science 2: 93-98.
Aziz, H.A., Ling, S.Y. & Umar, M. 2012. Treatment of
textile wastewater using Hibiscus rosa-sinensis (Bunga Raya) leaf
extract as coagulant. The 5th ASEAN Civil Engineering Conference (ACEC), the
5th ASEAN Environmental Engineering Conference (AEEC)& the 3rd Seminar on
Asian Water Environment (Asian Core Program of JSPS, NRCT & ERDT). 25-26
October. The Windsor Plaza, Ho Chi Minh City, Vietnam. pp. 1-17.
Birima, A.H., Hammad, H.A., Desa, M.N.M. & Muda, Z.C.
2013. Extraction of natural coagulant from peanut seeds for treatment of turbid
water. IOP Conference Series: Earth and Environmental Science 1: 1-4.
Bories, C., Borredon, M.E., Vedrenne, E., Vilarem, G. &
Agamuthu, P. 2009. Challenges and opportunities in agro-waste management: An
Asian perspective what is agro waste? Journal of Environmental Management 143:
186-196.
Camacho, F.P., Sousa, V.S., Bergamasco, R. & Teixeira,
M.R. 2017. The use of Moringa oleifera as a natural coagulant in surface
water treatment. Chemical Engineering Journal 313: 226-237.
Chi, F.H. & Cheng, W.P. 2006. Use of chitosan as
coagulant to treat wastewater from milk processing plant. Journal of
Polymers and the Environment 14(4): 411-417.
Choy, S.Y., Prasad, K.M.N., Wu, T.Y., Raghunandan, M.E.
& Ramanan, R.N. 2014. Utilization of plant-based natural coagulants as
future alternatives towards sustainable water clarification. Journal of
Environmental Sciences (China) 26(11): 2178-2189.
Corcoran, E., Nellemann, C., Baker, E., Bos, R., Osborn, D.
& Savelli, H. 2010. Sick water? The central role of wastewater management
in sustainable development. A Rapid Response Assessment. United Nations
Environment Programme, UN-HABITAT, GRID-Arendal.
Concentration Oily Wastewater Treatment. Chemical
Engineering Research and Design 119: 23-32.
De Souza, M.T.F., Ambrosio, E., De Almeida, C.A., De Souza,
T.K.F., Santos, F.L.B., De Cinque, V.A. & Garcia, J.C. 2014. The use of a
natural coagulant (Opuntia ficus-indica) in the removal for organic
materials of textile effluents. Environmental Monitoring and Assessment 186(8):
5261- 5271.
Debora, J., Theodoro, P., Lenz, G.F., Zara, R.F. &
Bergamasco, R. 2013. Coagulants and natural polymers: Perspectives for the
treatment of water. Plastic and Polymer Technology 2(3): 55-62.
Fatehah, M.O., Hossain, S. & Teng, T.T. 2013.
Semiconductor wastewater treatment using tapioca starch as a natural coagulant. Journal of Water Resource and Protection 5(11): 1018-1026.
Gani, P., Mohamed-Sunar, N., Matias-peralta, H.,
Abdul-Latiff, A.A., Parjo, U.K. & Oyekanmi, A.A. 2017. Green approach in
the bio-removal of heavy metals from wastewaters. MATEC Web of Conferences 103(ISCEE
2017): 1-8.
Ghafari, S., Hamidi, A.A. & Bashir, M.J.K. 2010. The use
of poly-aluminum chloride and alum for the treatment of partially stabilized
leachate: A comparative study. Desalination 257(1-3): 110-116.
Ghebremichael, K.A., Gunaratna, K.R., Henriksson, H.,
Brumer, H. & Dalhammar, G. 2005. A simple purification and activity assay
of the coagulant protein from Moringa oleifera seed. Water Research 39(11):
2338-2344.
Goh, P.S. & Ismail, A.F. 2018. A review on inorganic
membranes for desalination and wastewater treatment. Desalination 434:
60-80.
Hendrawati, H., Yuliastri, I.R., Nurhasni, R.E., Effendi, H.
& Darusman, L.K. 2016. The use of Moringa oleifera seed powder as
coagulant to improve the quality of wastewater and ground water. IOP
Conference Series: Earth and Environmental Science 31: 012033.
Heuzé, V., Tran, G., Archimède, H., Régnier, C.,
Bastianelli, D. & Lebas, F. 2016. Cassava peels, cassava pomace and other
cassava by-products. Feedipedia, a Programme by INRA, CIRAD, AFZ and FAO. http://www.feedipedia.org/node/526.
Hesami, F., Bina, B. & Ebrahimi, A. 2014. The
effectiveness of chitosan as coagulant aid in turbidity removal from water. International Journal of Environmental Health Engineering 3(1): 46-51.
Hosny,
R., Fathy, M., Ramzi, M., Moghny, T.A., Desouky, S.E.M. & Shama, S.A. 2016.
Treatment of the oily produced water (OPW) using coagulant mixtures. Egyptian
Journal of Petroleum 25(3): 391-396.
Howeler,
R.H., Oates, C.G. & Allem, A.C. 2001. Impact of cassava processing on the
environment. Proceedings of the Validation Forum on the Global Cassava
Development Strategy Strategic Environmental Assessment. p. 136.
http:// www.fao.org/docrep/007/y2413e/y2413e0d.htm.
Huang,
X., Gao, B., Wang, Y., Yue, Q., Li Q. & Zhang, Y. 2014. Coagulation
performance and flocs properties of a new composite coagulant:
Polytitanium-silicate-sulfate. Chemical Engineering Journal 245:
173-179.
Jadhav,
M.V. & Mahajan, Y.S. 2013. Investigation of the performance of chitosan as
a coagulant for flocculation of local clay suspensions of different
turbidities. KSCE Journal of Civil Engineering 17(2): 328-334.
Jiang,
J.Q. 2001. Development of coagulation theory and pre-polymerized coagulants for
water treatment. Separation and Purification Methods 30(1): 127-141.
Jones,
D.L., Freeman, C. & Sánchez-Rodríguez, A.R. 2017. Waste water treatment. Encyclopedia
of Applied Plant Sciences 3: 352-362.
Kakoi,
B., Kaluli, J.W., Ndiba, P. & Thiong’o, G. 2016. Banana pith as a natural
coagulant for polluted river water. Ecological Engineering 95: 699-705.
Kalpana,
V.N., Sravani, N., Vigneshwari, T. & Rajeswari, V.D. 2016. An inexpensive
substrate for the production of alkaline protease by Bacillus sp. and
its application studies of Manihot esculenta. Der Pharmacia Lettre 8(1):
220-232.
Kumar,
V., Othman, N. & Mohd-Asharuddin, S. 2017. Applications of natural
coagulants to treat wastewater - A review. MATEC Web of Conferences 103(ISCEE
2017).
Lewis,
L. 2017. Cholera, dengue fever, and malaria: The unquestionable link to water. The
Water Project. https://
thewaterproject.org/water-scarcity/cholera-dengue-fever-malaria-water. Accessed
on November 2, 2017.
Lee,
K.E., Morad, N., Teng, T.T. & Poh, B.T. 2012. Development, characterization
and the application of hybrid materials in coagulation/flocculation of
wastewater: A review. Chemical Engineering Journal 203: 370-386.
Marañón,
E, Castrillón, L., Fernández-Nava, Y. & Fernández- Méndez, A. 2010. Colour,
turbidity and COD removal from old landfill leachate by
coagulation-flocculation treatment. Waste Management & Research: The
Journal of the International Solid Wastes and Public Cleansing Association
(ISWA) 28(8): 731-737.
Maryam,
B. & Büyükgüngör, H. 2017. Wastewater reclamation and reuse trends in
Turkey: Opportunities and challenges. Journal of Water Process Engineering https://doi.
org/10.1016/j.jwpe.2017.10.001.
Mohammadi,
A.S., Mobarakian, A., Taherkhani, F. & Asgari, G. 2014. Effect of chitosan as
a coagulant aid combined with poly-aluminum chloride removing of turbidity from
drinking water. Avicenna J. Environ. Health Eng. 1(1): 0-4.
Mohan,
S.M. 2014. Use of naturalized coagulants in removing laundry waste surfactant
using various unit processes in lab-scale. Journal of Environmental
Management 136: 103-111.
Mohd-Asharuddin,
S., Othman, N., Mohd-Zin, N.S. & Tajarudin, H.A. 2017. A chemical and
morphological study of cassava peel: A potential waste as coagulant aid. MATEC
Web of Conferences 103(ISCEE 2017).
Mohd-Zin,
N.S., Hamidi, A.A. & Tajudin, S.A.A. 2016. Performance of tapioca starch in
removing suspended solid, colour and ammonia from real partially stabilized
leachate by coagulation-flocculation method. ARPN Journal of Engineering and
Applied Sciences 11(4): 2543-2546.
Mohd-Zin,
N.S., Hamidi, A.A., Adlan, M.N., Ariffin, A., Yusoff, M.S. & Dahlan, I.
2014. Treatability study of partially stabilized leachate by composite
coagulant (prehydrolyzed iron and tapioca flour). International Journal of
Scientific Research in Knowledge 2(7): 313-319.
Mohd-Zin,
N.S., Hamidi, A.A., Adlan, M.N., Ariffin, A., Yusoff, M.S. & Dahlan, I.
2015. A comparative study of floc and sludge of leachate under different types
of coagulants. Applied Mechanics and Materials 802: 406-411.
Moussas,
P.A. & Zouboulis, A.I. 2009. A new inorganic-organic composite coagulant,
consisting of polyferric sulphate (PFS) and polyacrylamide (PAA). Water
Research 43(14): 3511-3524.
Ni,
F., Peng, X., He, J., Yu, L., Zhao, J. & Luan, Z. 2012. Preparation and
characterization of composite bioflocculants in comparison with dual-coagulants
for the treatment of kaolin suspension. Chemical Engineering Journal 213:
195-202.
Omotosho,
O. 2016. Mitigation of nitrate pollution in wastewater: A case study of the
treatment of cassava processing effluent using cassava peel carbon material. International
Journal of Environmental, Chemical, Ecological, Geological and Geophysical
Engineering 9: 399-404.
Othman,
Z., Bhatia, S. & Ahmad, A.L. 2008. Influence of the settleability
parameters for palm oil mill effluent (POME) pre-treatment by using Moringa
oleifera seeds as an environmental friendly coagulant. International
Conference on Environment. pp. 1-9.
Pondja,
E.A.J., Persson, K.M. & Matsinhe, N.P. 2017. The potential use of cassava
peel for treatment of mine water in Mozambique. Journal of Environmental
Protection 8: 277-289.
Pontius,
F.W. 2016. Chitosan as a drinking water treatment coagulant. American
Journal of Civil Engineering 4(5): 205-215.
Qudsieh,
I.Y., Fakhru’l, R., Kabbashi, N.A., Mirghani, M.E.S., Fandi, K.G., Alam, M.Z.,
Muyibi, S.A. & Nasef, M.M. 2008. Preparation and characterization of a new
coagulant based on the sago starch biopolymer and its application in water
turbidity removal. Journal of Applied Polymer Science 109: 3140-3147.
Raschid-Sally,
L. & Jayakody, P. 2008. Drivers and characteristics of wastewater
agriculture in developing countries: Results from a global assessment, Colombo,
Sri Lanka. IWMI Research Report 127, Colombo: International Water
Management Institute. p. 35.
Rajasulochana,
P. & Preethy, P. 2016. Comparison on efficiency of various techniques in
treatment of waste and sewage water - A comprehensive review. Resource-Efficient
Technologies 2(4): 175-184.
Rasool,
M.A., Tavakoli, B., Chaibakhsh, N., Pendashteh, A.R. & Mirroshandel, A.S.
2016. Use of a plant-based coagulant in coagulation-ozonation combined
treatment of Leachate from a waste dumping site. Ecological Engineering 90:
431-437.
Rong, H., Gao, B., Li, J., Zhang, B., Sun,
S., Wang, Y., Yue, Q. & Li, Q. 2013. Floc characterization and membrane
fouling of polyferric-polymer dual/composite coagulants in coagulation/
ultrafiltration hybrid process. Journal of Colloid and Interface Science 412:
39-45.
Rui,
L.M., Daud, Z., Aziz, A. & Latif, A. 2012a. Coagulation-flocculation in
leachate treatment by using micro sand. International Journal of Engineering 2(5): 227-236.
Rui,
L.M., Daud, Z., Aziz, A. & Latif, A. 2012b. Advanced science information technology
treatment of leachate by coagulation-flocculation using different coagulants
and polymer: A review. International Journal on Advanced Science Engineering
Information Technology 2(2): 4-7.
Rusdizal,
N., Hamidi, A.A. & Fatehah, M.O. 2015. Potential use of polyaluminium
chloride and tobacco leaf as coagulant and coagulant aid in post-treatment of
landfill leachate. Avicenna J. Environmental Health Engineering doi:
10.17795/ ajehe-5836.
Saharudin,
N.F.A. & Nithyanandam, R. 2014. Wastewater treatment by using natural
coagulant. 2nd Eureca. pp. 2-3.
Sánchez-Martín,
J., Beltrán-Heredia, J. & Peres, J.A. 2012. Improvement of the flocculation
process in water treatment by using Moringa oleifera seeds extract. Brazilian
Journal of Chemical Engineering 29(3): 495-501.
Saravanan,
J., Priyadharshini, D., Soundammal, A., Sudha, G. & Suriyakala, K. 2017.
Wastewater treatment using natural coagulants. SSRG International Journal of
Civil Engineering 4(3): 40-42.
Shak,
K.P.Y. & Wu, T.Y. 2015. Optimized use of alum together with unmodified Cassia
obtusifolia seed gum as a coagulant aid in treatment of palm oil mill
effluent under natural pH of wastewater. Industrial Crops and Products 76:
1169-1178.
Shamsnejati,
S., Chaibakhsh, N., Pendashteh, A.R. & Hayeripour, S. 2015. Mucilaginous
seed of Ocimum basilicum as a natural coagulant for textile wastewater
treatment. Industrial Crops and Products 69: 40-47.
Shan,
T.C., Matar, M.A., Makky, E.A. & Ali, E.N. 2017. The use of Moringa
oleifera seed as a natural coagulant for wastewater treatment and heavy
metals removal. Applied Water Science 7(3): 1369-1376.
Shen,
Y.H. & Dempsey, B.A. 1998. Synthesis and speciation of polyaluminum
chloride for water treatment. Environment International 24(8): 899-910.
Simate,
G.S. & Ndlovu, S. 2015. The removal of heavy metals in a packed bed column
using immobilized cassava peel waste biomass. Journal of Industrial and
Engineering Chemistry 21: 635-643.
Subramonian,
W., Wu, T.Y. & Chai, S.P. 2014. A comprehensive study on coagulant performance
and floc characterization of natural Cassia obtusifolia seed gum in
treatment of raw pulp and paper mill effluent. Industrial Crops and Products 61: 317-324.
Sun,
Y., Zhu, C., Zheng, H., Sun, W., Xu, Y., Xiao, X., You, Z. & Liu, C. 2017.
Characterization and coagulation behavior of polymeric aluminum ferric silicate
for high-concentration oily wastewater treatment. Chemical Engineering
Research and Design 119: 23-32.
Syafalni,
L.H.K., Ismail, N., Abustan, I., Murshed, M.F. & Ahmad, A. 2012. Treatment
of landfill leachate by using lateritic soil as a natural coagulant. Journal
of Environmental Management 112: 353-359.
Teh,
C.Y., Wu, T.Y. & Juan, J.C. 2014. Potential use of rice starch in
coagulation-flocculation process of agro-industrial wastewater: Treatment
performance and flocs characterization. Ecological Engineering 71:
509-519.
Teixeira,
M.R., Camacho, F.P., Sousa, V.S. & Bergamasco, R. 2017. Green technologies
for cyanobacteria and natural organic matter water treatment using natural
based products. Journal of Cleaner Production 162: 484-490.
Tzoupanos,
N.D. & Zouboulis, A.I. 2011. Preparation, characterisation and application
of novel composite coagulants for surface water treatment. Water Research 45(12):
3614- 3626.
Verma,
M. & Kumar, N.R. 2016. Can coagulation–flocculation be an effective
pre-treatment option for landfill leachate and municipal wastewater
co-treatment? Perspectives in Science 8: 492-494.
Vieira,
R.B., Vieira, P.A., Cardoso, S.L., Ribeiro, E.J. & Cardoso, V.L. 2012.
Sedimentation of mixed cultures using natural coagulants for the treatment of
effluents generated in terrestrial fuel distribution terminals. Journal of
Hazardous Materials 231-232: 98-104.
Wang,
B., Shui, Y., He, M. & Liu, P. 2017a. Comparison of flocs characteristics
using before and after composite coagulants under different coagulation
mechanisms. Biochemical Engineering Journal 121: 107-117.
Wang,
J., Yao, W., Gu, P., Yu, S., Wang, X., Du, Y., Wang, H., Chen, Z., Hayat, T.
& Wang, X. 2017b. Efficient coagulation of graphene oxide on chitosan-metal
oxide composites from aqueous solutions. Cellulose 24(2): 851-861.
World
Health Organization (WHO). 2017. Monitoring Health for the SDGs. World
Health Organization. doi:10.1017/ CBO9781107415324.004.
WWAP.
2016. The United Nations World Water Development Report 2016: Facts and
Figures. 12. doi:10.1017/ CBO9781107415324.004.
Yin,
C.Y. 2010. Emerging usage of plant-based coagulants for water and wastewater
treatment. Process Biochemistry 45(9): 1437-1444.
Yusoff,
M.S. & Mohamad Zuki, N.A. 2015. Optimum of treatment condition for Artocarpus
heterophyllus seeds starch as natural coagulant aid in landfill leachate
treatment by RSM. Applied Mechanics and Materials 802: 484-489.
Zainol,
N.A., Hamidi, A.A., Yusoff, M.S. & Umar, M. 2011. The use of polyaluminum
chloride for the treatment of landfill leachate via coagulation and
flocculation processes. Research Journal of Chemical Sciences 1(3):
34-39.
Zayadi,
N., Othman, N. & Hamdan, R. 2016. A potential waste to be selected as media
for metal and nutrient removal. IOP Conference Series: Materials Science and
Engineering 136(1): 1-8.
Zazouli,
M.A. & Yousefi, Z. 2008. Removal of heavy metals from solid wastes
leachates coagulation-floculation process. Journal of Applied Sciences 8(11):
2142-2147.
Zhu,
G., Zheng, H., Chen, W., Fan, W., Zhang, P. & Tshukudu, T. 2012.
Preparation of a composite coagulant: Polymeric aluminum ferric sulfate (PAFS)
for wastewater treatment. Desalination 285: 315-323.
Zonoozi,
M.H., Moghaddam, M.R.A. & Arami, M. 2011. Study on the removal of acid dyes
using chitosan as a natural coagulant/ coagulant aid. Water Science and
Technology 63(3): 403-409.
*Pengarang
untuk surat-menyurat; email: nursha@uthm.edu.my
|