Sains Malaysiana 51(2)(2022): 507-517

http://doi.org/10.17576/jsm-2022-5102-15

 

Study of CO2 Adsorption Time for Carbonate Species and Linear CO2 Formations onto Bimetallic CaO/Fe2O3 by Infrared Spectroscopy

(Kajian Masa Penjerapan CO2 untuk Pembentukan Spesies Karbonat dan CO2 Linear pada Dwilogam CaO/Fe2O3 oleh Spektroskopi Inframerah)

 

AZIZUL HAKIM LAHURI1* & MOHD AMBAR YARMO2

 

1Department of Science and Technology, Universiti Putra Malaysia Bintulu Kampus, P.O Box 396, Nyabau Road, 97008 Bintulu, Sarawak, Malaysia

 

2Department of Chemical Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

 

Diserahkan: 23 Disember 2020/Diterima: 15 Jun 2021

 

ABSTRACT

The CO2 adsorption time for carbonate species and linear CO2 formation onto bimetallic CaO/Fe2O3 was investigated. The total basicity for CaO/Fe2O3 was 52.85 cm3g-1 which is located at a medium basic site with maximum CO desorption temperature at 454 . The CO2 adsorption was conducted by using a fluidized bed reactor at 4, 12, 24 and 36 h. The element distribution on the adsorbent showed carbonate formation through an increment of the C element when the CO2 adsorption time was longer. At 4 h of CO2 adsorption, the adsorbent is capable of generating bicarbonate, monodentate carbonate and bidentate carbonate species. The vibrational modes of the physisorbed linear CO2 for CO2 absorbed product at the absorption region of 2240-2402 cm-1 was identified after 36 h of CO2 adsorption. The absorption bands were assigned according to the adjacent CO2 molecule interactions giving formation of the core layer and second layer linear CO2 on the CaO/Fe2O3 surfaces. The results of the present work show that the addition of CaO on the Fe2O3 surfaces enhanced the basic site of the adsorbent which could generate several carbonate species and CO2 adsorbed products at ambient condition.

 

Keywords: Bimetallic; calcium oxide; carbonate formation; CO2 capture; iron(III) oxide

 

ABSTRAK

Masa penjerapan CO2 bagi pembentukan karbonat dan CO2 linear di atas dwilogam CaO/Fe2O3telah dikaji. Jumlah kebesan bagi CaO/Fe2O3 adalah sebanyak 52.85 cm3g-1 terletak di tapak bes medium dengan suhu penyahjerapan CO maksimum pada 454 . Penjerapan CO2 dilakukan dengan menggunakan reaktor lapisan terbendalir selama 4, 12, 24 dan 36 jam. Taburan unsur pada penjerap telah menunjukkan bukti pembentukan karbonat melalui peningkatan bagi unsur C apabila masa penjerapan CO2 semakin lama. Selepas penjerapan CO2 selama 4 jam, penjerap berkeupayaan dalam menghasilkan spesies bikarbonat, karbonat monodentat dan karbonat bidentat. Mod getaran bagi CO2 linear yang terjerap secara fizikal untuk hasil CO2 terjerap pada bahagian serapan 2240-2402 cm-1 adalah jelas dikenal pasti setelah 36 jam penjerapan CO2. Jalur serapan ditentukan berdasarkan interaksi molekul CO2 berdekatan yang memberikan pembentukan lapisan teras dan lapisan kedua CO2 linear pada permukaan CaO/Fe2O3. Hasil kajian ini menunjukkan penambahan CaO pada permukaan Fe2O3 telah memperbaiki tapak bes bagi penjerap yang membolehkan pembentukan spesies karbonat dan CO2 linear pada keadaan ambien.

 

Kata kunci: Dwilogam; ferum(III) oksida; kalsium oksida; pembentukan karbonat; penjerapan CO2

 

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*Pengarang untuk surat-menyurat; email: azizulhakim@upm.edu.my

 

 

   

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