Malaysian Journal of Analytical Sciences Vol 19 No 1 (2015): 155 – 162
EFFECT OF CHITOSAN BINDER ON WATER ABSORPTION OF EMPTY
FRUIT BUNCHES FILTER MEDIA
(Kesan Kitosan Sebagai
Pengikat Keatas Penjerapan Air Media Penapis Tandan Kosong Kelapa Sawit)
Aziatul Niza Sadikin1, 3*, Mohd Ghazali
Mohd Nawawi1, 3, Norasikin Othman1, 3, Umi Aisah Asli1,
4,
Roshafima Rasit Ali1, 5, Hasrinah
Hasbullah2, 6, Norazana Ibrahim2, 7
1Faculty of Chemical Engineering,
2Faculty of Petroleum & Renewable Engineering,
3Center of Lipid and Applied Research,
4Institute Hydrogen Economy,
5Composite Centre,
6Advanced Membrane Technology Research Centre,
7Gas Technology Centre,
Universiti
Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia
*Corresponding author: aziatulniza@cheme.utm.my
Abstract
The potential of chitosan as filter media binder was
investigated in this study. Chitosan solution with different concentrations
were applied to the empty fruit bunches using two different deposition
techniques, namely, spray method and addition method. In this study, a water
absorption test was used to study the sorption behaviour of empty fruit bunches
filter media. The water absorption study showed that the water uptake for empty
fruit bunches filter media without the chitosan binder increases with time,
until the water sorption reaches the equilibrium state. It was observed that
the water uptake decreased from 23% to 14% for the chitosan-filled filter media
as compared to binder-less filter media, over the duration of 24 hours. For 1%
chitosan concentration, the water uptake is higher compared to 3%
chitosan-filled filter media. The water absorption is relatively lower for
filter media with a higher concentration of chitosan due to the high
compatibility achieved at this interfacial region between empty fruit bunches
fibres and chitosan. Alkali-treated filter media showed the lowest water uptake
compared to diethyl ether, ethanol and hot water pretreatment methods.
Keywords:
empty fruit bunch, filter media, chitosan, water
absorption
Abstrak
Potensi kitosan sebagai
pengikat media penapis telah dikaji dalam kajian ini. Pelarut kitosan dengan
kepekatan yang berbeza telah digunakan untuk tandan kosong buah kelapa sawit
dengan menggunakan dua teknik penyaduran yang berbeza, iaitu, kaedah semburan
dan kaedah tambahan. Dalam kajian ini, ujian penyerapan air digunakan untuk
mengkaji kelakuan serapan media penapis dari tandan kosong buah kelapa sawit.
Kajian penyerapan air menunjukkan bahawa pengambilan air untuk tandan buah
kosong penapis media tanpa pengikat kitosan meningkat dengan masa, sehingga
penyerapan air mencapai keseimbangan. Diperhatikan bahawa pengambilan air
sepanjang 24 jam, menurun daripada 23% kepada 14% untuk media penapis berisi
kitosan berbanding media penapis tanpa pengikat. Untuk kepekatan 1% kitosan,
serabut media mempunyai jurang lebar yang lebih tinggi berbanding dengan
penapis kitosan yang berkepekatan 4%. Penyerapan air untuk penapis media dengan
kepekatan yang lebih tinggi adalah rendah kerana keserasian yang tinggi dicapai
pada rantau di antara permukaan serat tandan kosong kelapa sawit dan kitosan.
Kata kunci: tandan kosong kelapa sawit, media penapis, kitosan,
penjerapan air
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